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Following sidwick.s rule of EAN, Co(CO)(...

Following sidwick.s rule of EAN, `Co(CO)_(x)` will be:

A

`Co(CO)_(4)`

B

`Co(CO)_(3)`

C

`Co(CO)_(6)`

D

`Co(CO)_(10)`

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The correct Answer is:
To solve the question regarding the effective atomic number (EAN) of the complex `Co(CO)_(x)` using Sidwick's rule, we will follow these steps: ### Step 1: Understand Sidwick's Rule Sidwick's rule states that the effective atomic number (EAN) of a metal complex can be calculated using the formula: \[ \text{EAN} = Z - O + 2C \] where: - \( Z \) is the atomic number of the central metal atom, - \( O \) is the oxidation state of the metal, - \( C \) is the coordination number (the number of ligands attached to the metal). ### Step 2: Identify the Components For the complex `Co(CO)_(x)`: - The central metal atom is cobalt (Co). - The atomic number of cobalt (Co) is 27. - The oxidation state of cobalt in this case is 0 (since CO is a neutral ligand). - The coordination number \( C \) is represented by \( x \), which is what we need to find. ### Step 3: Set Up the Equation According to Sidwick's rule, we want the EAN to equal the atomic number of the nearest noble gas. The nearest noble gas to cobalt is krypton, which has an atomic number of 36. Therefore, we set up the equation: \[ 36 = 27 - 0 + 2x \] ### Step 4: Solve for \( x \) Now, we can simplify and solve for \( x \): 1. Substitute the values into the equation: \[ 36 = 27 + 2x \] 2. Rearranging gives: \[ 36 - 27 = 2x \] \[ 9 = 2x \] 3. Dividing both sides by 2: \[ x = \frac{9}{2} \] \[ x = 4.5 \] ### Step 5: Interpret the Result Since \( x \) must be a whole number (as it represents the number of CO ligands), we round \( x \) to the nearest whole number. Therefore, we conclude that: \[ x = 4 \] ### Final Answer Thus, the complex can be represented as: \[ Co(CO)_{4} \]

To solve the question regarding the effective atomic number (EAN) of the complex `Co(CO)_(x)` using Sidwick's rule, we will follow these steps: ### Step 1: Understand Sidwick's Rule Sidwick's rule states that the effective atomic number (EAN) of a metal complex can be calculated using the formula: \[ \text{EAN} = Z - O + 2C \] where: - \( Z \) is the atomic number of the central metal atom, - \( O \) is the oxidation state of the metal, ...
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ALLEN-INORGANIC CHEMISTRY-COORDINATION COMPOUNDS & d-BLOCK COMPOUNDS
  1. Select incorrect match for [M(H(2)O)(6)]^(2+) complex.

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  2. Which of the following is non-conducting?

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  3. Following sidwick.s rule of EAN, Co(CO)(x) will be:

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  4. Which of the following cannot show linkage isomerism ?

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  5. [Pt(NH(3))(4)][CuCl(4)] and [Cu(NH(3))(4)][PtCl(4)] are known as

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  6. [Co(NH(3))(5)NO(2)]Cl(2) and [Co(NH(3))(5)ONO]Cl(2) are related to e...

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  7. The number of geometrical isomers of the complex [Co(NO(2))(3)(NH(3))(...

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  8. Name the type of isomerism exibited by the following isomers : (1) ...

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  9. Which of following isomers of [M(NH(3))(2)Cl(2)] would react with sil...

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  10. Which of the following complex will follow EAN rule ?

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  11. Identify the geometrical isomers of the following:-

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  12. Which of the following will show optical isomers? (I) cis-[Co(NH(3))...

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  13. Which of the following isomerism is/are not shown by the complex [Co(C...

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  14. Three arrangements are shown for the complex [Co(e n) (NH(3))(2)Cl(2)]...

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  15. Which kind of isomerism is exhibited by octahedral [Co(NH(3))(2)Br(2)]...

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  16. Which of the following has an option isomer ?

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  17. Which of the following pairs represents linkage isomers ?

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  18. Select the correct statement from the following?

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  19. [Fe(e n)(2)(H(2)O)(2)]^(2+) +e n to complex (x). The correct statement...

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  20. Which of the following complexes show geometrical as well as optical i...

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