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[Fe(e n)(2)(H(2)O)(2)]^(2+) +e n to comp...

`[Fe(e n)_(2)(H_(2)O)_(2)]^(2+) +e n to` complex (x). The correct statement about the complex (x) it is

A

a low spin complex

B

diamagnetic

C

shows geometrical isomerism

D

(1) and (2) both

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AI Generated Solution

The correct Answer is:
To solve the question regarding the complex \([Fe(en)_2(H_2O)_2]^{2+} + en\) leading to complex \(x\), we will follow these steps: ### Step 1: Identify the initial complex The initial complex is \([Fe(en)_2(H_2O)_2]^{2+}\). Here, \(Fe\) is in the +2 oxidation state, and the ligands are ethylenediamine (en) and water (H2O). ### Step 2: Determine the coordination number and geometry In this complex, \(Fe\) is coordinated to 4 ligands (2 en and 2 H2O). Ethylenediamine is a bidentate ligand, which means it forms two bonds with the metal ion. The coordination number is 6 (2 from each en and 2 from H2O). The geometry of a coordination number of 6 is typically octahedral. ### Step 3: Analyze the ligand field Ethylenediamine (en) is a strong field ligand, which means it has a strong tendency to cause pairing of electrons in the d-orbitals. This results in a low-spin configuration. ### Step 4: Determine the electronic configuration For \(Fe^{2+}\), the electronic configuration is \([Ar] 3d^6\). In the presence of strong field ligands like en, the electrons will pair up in the lower energy \(t_{2g}\) orbitals, leading to a configuration of \(t_{2g}^6\) and no unpaired electrons. ### Step 5: Conclude the nature of the complex Since all the electrons are paired, the complex is diamagnetic. Additionally, due to the strong field ligands and the pairing of electrons, it is classified as a low-spin complex. ### Final Answer The correct statement about complex \(x\) is that it is a low-spin, diamagnetic complex.

To solve the question regarding the complex \([Fe(en)_2(H_2O)_2]^{2+} + en\) leading to complex \(x\), we will follow these steps: ### Step 1: Identify the initial complex The initial complex is \([Fe(en)_2(H_2O)_2]^{2+}\). Here, \(Fe\) is in the +2 oxidation state, and the ligands are ethylenediamine (en) and water (H2O). ### Step 2: Determine the coordination number and geometry In this complex, \(Fe\) is coordinated to 4 ligands (2 en and 2 H2O). Ethylenediamine is a bidentate ligand, which means it forms two bonds with the metal ion. The coordination number is 6 (2 from each en and 2 from H2O). The geometry of a coordination number of 6 is typically octahedral. ...
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ALLEN-INORGANIC CHEMISTRY-COORDINATION COMPOUNDS & d-BLOCK COMPOUNDS
  1. Which of the following pairs represents linkage isomers ?

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  2. Select the correct statement from the following?

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  3. [Fe(e n)(2)(H(2)O)(2)]^(2+) +e n to complex (x). The correct statement...

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  4. Which of the following complexes show geometrical as well as optical i...

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  5. The total number of possible isomers for the complex compound [Cu^(II)...

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  6. [Co(e n)(3)]^(3+) ion is expected to show :-

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  7. How many geometrical isomers are there for [Co(NH(3))(2)Cl(4)]^(-), a...

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  8. How many isomers are possible for the complex ion [Cr(NH(3))(3)Cl(3)] ...

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  9. For the square planar complex [Pt(NH(3))(NH(2)OH)(py)(No(2))]^(o+) how...

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  10. Isomerisms exhibited by [Cr(NH3)2(H2O)2Cl2]^+ are

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  11. Which of the following is true for the complex Co(NO(2) )(Cl)(2) .5NH(...

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  12. The total No. of isomers possible for the complex [Co (e n)(2)Cl(2)] i...

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  13. The complex [Pt(NH3)4]2+ has ......structure :

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  14. Which of the following is not correctly matched

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  15. In complexes more stability is shown by:-

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  16. when MnO2 is fused with KOH and KNO3 , a coloured compound is formed ....

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  17. Which of the following is not correctly matched

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  18. Which of the following is incorrectly matched complex?

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  19. Which of the following is correctly matched?

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  20. The complex [Fe(H(2)O)(5)NO]^(2+) is formed in Brown ring test for nit...

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