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The total No. of isomers possible for th...

The total No. of isomers possible for the complex `[Co (e n)_(2)Cl_(2)]` is :-

A

2

B

3

C

4

D

5

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The correct Answer is:
To determine the total number of isomers for the complex \([Co(en)_2Cl_2]\), we can follow these steps: ### Step 1: Identify the Coordination Number and Geometry The complex \([Co(en)_2Cl_2]\) has a coordination number of 6 because it contains two bidentate ethylenediamine (en) ligands and two monodentate chloride (Cl) ligands. The geometry of such a complex is octahedral. **Hint:** Remember that the coordination number indicates how many ligand atoms are bonded to the central metal atom. ### Step 2: Determine Possible Geometrical Isomers In an octahedral complex, we can have geometrical isomers, specifically cis and trans forms. - **Cis Isomer:** In the cis configuration, the two ethylenediamine ligands are adjacent to each other. - **Trans Isomer:** In the trans configuration, the two ethylenediamine ligands are opposite each other. **Hint:** Visualize the octahedral structure to help differentiate between cis and trans configurations. ### Step 3: Analyze Optical Isomerism The cis isomer can exhibit optical isomerism because it lacks a plane of symmetry. This means that the cis isomer can exist in two forms: the D (dextrorotatory) form and the L (levorotatory) form. - **Optical Isomers of Cis:** The cis isomer has two optical isomers (D and L). - **Optical Isomers of Trans:** The trans isomer does not have optical isomers because it has a plane of symmetry. **Hint:** Remember that optical isomers are non-superimposable mirror images and require the absence of symmetry. ### Step 4: Count Total Isomers Now, we can summarize the isomers: - **Cis Isomer:** 2 (D and L forms) - **Trans Isomer:** 1 Thus, the total number of isomers is: \[ \text{Total Isomers} = 2 \text{ (cis)} + 1 \text{ (trans)} = 3 \] **Hint:** Keep track of both geometrical and optical isomers to ensure you count all possible variations. ### Conclusion The total number of isomers possible for the complex \([Co(en)_2Cl_2]\) is **3**. **Final Answer:** 3

To determine the total number of isomers for the complex \([Co(en)_2Cl_2]\), we can follow these steps: ### Step 1: Identify the Coordination Number and Geometry The complex \([Co(en)_2Cl_2]\) has a coordination number of 6 because it contains two bidentate ethylenediamine (en) ligands and two monodentate chloride (Cl) ligands. The geometry of such a complex is octahedral. **Hint:** Remember that the coordination number indicates how many ligand atoms are bonded to the central metal atom. ### Step 2: Determine Possible Geometrical Isomers ...
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ALLEN-INORGANIC CHEMISTRY-COORDINATION COMPOUNDS & d-BLOCK COMPOUNDS
  1. Isomerisms exhibited by [Cr(NH3)2(H2O)2Cl2]^+ are

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  2. Which of the following is true for the complex Co(NO(2) )(Cl)(2) .5NH(...

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  3. The total No. of isomers possible for the complex [Co (e n)(2)Cl(2)] i...

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  4. The complex [Pt(NH3)4]2+ has ......structure :

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  5. Which of the following is not correctly matched

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  6. In complexes more stability is shown by:-

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  7. when MnO2 is fused with KOH and KNO3 , a coloured compound is formed ....

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  8. Which of the following is not correctly matched

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  9. Which of the following is incorrectly matched complex?

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  10. Which of the following is correctly matched?

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  11. The complex [Fe(H(2)O)(5)NO]^(2+) is formed in Brown ring test for nit...

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  12. Which are the correct statements ?

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  13. Which of the following is/are inner orbital complex as well as paramag...

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  14. In nitroprusside ion the iron and NO exist as Fe (II) and NO^(+) rathe...

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  15. Na(2)S+Na(2)[Fe(CN)(5)NO]rarrNa(4)[Fe(NH)(5)NOS], oxidation number of ...

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  16. Which of the following are square planar complexes ? (i) [AuCl(4)]^(...

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  17. The crystal field -splitting for Cr^(3+) ion in octahedral field chang...

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  18. Which of the following is the high spin complex?

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  19. Which has maximum paramagnetic nature ?

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  20. Which of the following order of CFSE is incorrect?

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