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Which of the following is/are inner orbi...

Which of the following is/are inner orbital complex as well as paramagnetic with magnetic moment equal to 3.78 (approx) ?

A

`[Co(O X)_(3)]^(3-)`

B

`[Cr(NH_(3))_(6)]^(3+)`

C

`[Fe(H_(2)O)_(5)NO]^(2+)`

D

`[Zn(NH_(3))_(6)]^(2+)`

Text Solution

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The correct Answer is:
To determine which of the given complexes is an inner orbital complex as well as paramagnetic with a magnetic moment of approximately 3.78, we will analyze each complex step by step. ### Step 1: Identify the oxidation states and electronic configurations of the metal ions in the complexes. 1. **Cobalt (Co)**: - Oxidation state: +3 - Electronic configuration: Co (atomic number 27) → [Ar] 3d^6. 2. **Chromium (Cr)**: - Oxidation state: +3 - Electronic configuration: Cr (atomic number 24) → [Ar] 3d^5 4s^1 → 3d^3 in +3 state. 3. **Iron (Fe)**: - Oxidation state: +1 - Electronic configuration: Fe (atomic number 26) → [Ar] 3d^6 4s^2 → 3d^6 4s^1 in +1 state. 4. **Zinc (Zn)**: - Oxidation state: +2 - Electronic configuration: Zn (atomic number 30) → [Ar] 3d^10 4s^2.

To determine which of the given complexes is an inner orbital complex as well as paramagnetic with a magnetic moment of approximately 3.78, we will analyze each complex step by step. ### Step 1: Identify the oxidation states and electronic configurations of the metal ions in the complexes. 1. **Cobalt (Co)**: - Oxidation state: +3 - Electronic configuration: Co (atomic number 27) → [Ar] 3d^6. ...
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ALLEN-INORGANIC CHEMISTRY-COORDINATION COMPOUNDS & d-BLOCK COMPOUNDS
  1. The complex [Fe(H(2)O)(5)NO]^(2+) is formed in Brown ring test for nit...

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  2. Which are the correct statements ?

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  3. Which of the following is/are inner orbital complex as well as paramag...

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  4. In nitroprusside ion the iron and NO exist as Fe (II) and NO^(+) rathe...

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  5. Na(2)S+Na(2)[Fe(CN)(5)NO]rarrNa(4)[Fe(NH)(5)NOS], oxidation number of ...

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  6. Which of the following are square planar complexes ? (i) [AuCl(4)]^(...

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  7. The crystal field -splitting for Cr^(3+) ion in octahedral field chang...

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  8. Which of the following is the high spin complex?

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  9. Which has maximum paramagnetic nature ?

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  10. Which of the following order of CFSE is incorrect?

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  11. Which of the following is/are inner orbital complex as well as dimagne...

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  12. Which of the following is/are correct about [Cu(NH(3))(4)]SO(4) :

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  13. The hybridisation of [CoF(6)]^(3-) & [Co(C(2)O(4))(3)]^(3-) are :-

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  14. A complex of a certain metal ion has a magnetic moment of 4.90BM Anoth...

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  15. [Sc (H(2)O)(6)]^(3+) ion is :-

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  16. Which of the following complex compounds does not exhibits cis-trans i...

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  17. Which of the following correct?

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  18. Of the following complex ions, the one that probably has the largest o...

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  19. Which is not a pi-bonded complex ?

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  20. What is wrong about the compound K[Pt (eta^(2)-C(2)H(4))Cl(3)]

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