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[Sc (H(2)O)(6)]^(3+) ion is :-...

`[Sc (H_(2)O)_(6)]^(3+)` ion is :-

A

Coloured and paramagnetic

B

Colourless and paramagnetic

C

Colourless and diamagnetic

D

Coloured & octahedral

Text Solution

AI Generated Solution

The correct Answer is:
To determine the properties of the ion \([Sc(H_2O)_6]^{3+}\), we will analyze its electronic configuration, magnetic properties, and geometry step by step. ### Step 1: Identify the Atomic Number and Electronic Configuration of Scandium - Scandium (Sc) has an atomic number of 21. - The electronic configuration of Sc is: \[ \text{Sc: } [Ar] 3d^1 4s^2 \] **Hint:** Remember that the electronic configuration helps us understand the distribution of electrons in different energy levels. ### Step 2: Determine the Electronic Configuration of Scandium Ion - The ion \([Sc(H_2O)_6]^{3+}\) means that Scandium has lost 3 electrons. - Removing 3 electrons from the configuration \([Ar] 3d^1 4s^2\) results in: - The 2 electrons from the 4s subshell and 1 electron from the 3d subshell. - Therefore, the electronic configuration of \([Sc]^{3+}\) is: \[ \text{Sc}^{3+}: [Ar] 3d^0 4s^0 \] **Hint:** When forming cations, electrons are removed from the outermost shell first. ### Step 3: Analyze the Magnetic Properties - The configuration \([Ar] 3d^0 4s^0\) indicates that there are no unpaired electrons in the d subshell. - Since there are no unpaired electrons, the ion is classified as **diamagnetic**. **Hint:** Diamagnetic substances are those that have all their electrons paired and are not attracted to a magnetic field. ### Step 4: Determine the Color and Shape of the Complex - The complex \([Sc(H_2O)_6]^{3+}\) has 6 water molecules acting as ligands, which means it has an octahedral geometry. - The presence of 6 ligands and the absence of unpaired electrons typically results in the complex being **colorless**. **Hint:** The color of a transition metal complex is often due to the presence of unpaired electrons and the type of ligands. In this case, the absence of unpaired electrons leads to a colorless complex. ### Conclusion - The ion \([Sc(H_2O)_6]^{3+}\) is **diamagnetic** and **colorless**, and it has an **octahedral shape**. **Final Answer:** The correct option is **C: Diamagnetic and Colorless**.
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