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Select the incorrect statement on basis ...

Select the incorrect statement on basis of following conversion :-
`underset("Ore")underset("coloured")underset("Black")(X) underset("air")overset(KOH)tounderset("green")underset("Dark")(Y)overset(H^(o+))tounderset("agent")underset("an oxidising")(Z)+X`

A

X may be `MnO_(2)`

B

Y can be `K_(2)MnO_(4)`

C

Z can be `KMnO_(4)`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the conversion process described and identify the incorrect statement based on the given reactions. ### Step-by-Step Solution: 1. **Identify the Starting Material (X)**: - The black colored ore (X) is likely to be manganese dioxide (MnO2). 2. **Reaction with Potassium Hydroxide and Air**: - When MnO2 reacts with potassium hydroxide (KOH) in the presence of air (oxygen), it produces a green compound (Y). - The balanced reaction is: \[ 3 \text{MnO}_2 + 4 \text{KOH} + \text{O}_2 \rightarrow 2 \text{K}_2\text{MnO}_4 + 2 \text{H}_2\text{O} \] - Here, Y is potassium manganate (K2MnO4), which is green in color. 3. **Reaction of Y with Acid (H+)**: - When the green compound (Y, K2MnO4) is treated with an acid (H+), it converts to potassium permanganate (KMnO4, Z), which is purple. - The reaction can be represented as: \[ 2 \text{K}_2\text{MnO}_4 + 2 \text{H}^+ \rightarrow 2 \text{KMnO}_4 + \text{MnO}_2 + 2 \text{H}_2\text{O} \] 4. **Identify the Compounds**: - X = MnO2 (black) - Y = K2MnO4 (green) - Z = KMnO4 (purple, an oxidizing agent) 5. **Determine the Incorrect Statement**: - Based on the reactions and the colors of the compounds: - MnO2 is indeed black. - K2MnO4 is green. - KMnO4 is purple and acts as an oxidizing agent. - Any statement that contradicts these facts would be incorrect. ### Conclusion: The incorrect statement would be one that misrepresents the colors or the nature of the compounds involved in the reactions.
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