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Which of the following order of L.E. is ...

Which of the following order of L.E. is not correct :-

A

`Al_(2)O_(3) lt MgO lt Na_(2) O`

B

`NaF lt MgO lt ScN lt TiC`

C

`KBr lt LiF lt MgO`

D

`LiF gt NaF gt KF`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which order of lattice energy (L.E.) is incorrect, we need to analyze the given compounds based on the charges of their ions and their ionic sizes. Lattice energy is influenced by two main factors: the charge of the ions and the distance between them (interionic distance). ### Step-by-Step Solution: 1. **Understanding Lattice Energy**: - Lattice energy is directly proportional to the charge of the ions and inversely proportional to the distance between them. - Higher charges lead to higher lattice energy, while larger ionic sizes (greater interionic distance) lead to lower lattice energy. 2. **Analyzing Each Option**: - **Option D**: Lithium fluoride (LiF), sodium fluoride (NaF), potassium fluoride (KF) - All ions have the same charges (+1 and -1). - As we move down the group, the size of the cations increases (Li < Na < K), leading to increased interionic distance. - Therefore, the order of lattice energy should be: \[ \text{LiF} > \text{NaF} > \text{KF} \] - This order is correct. - **Option C**: Potassium bromide (KBr), lithium fluoride (LiF), magnesium oxide (MgO) - Charges: K (+1), Br (-1); Li (+1), F (-1); Mg (+2), O (-2). - MgO has the highest charge, thus it should have the highest lattice energy. - KBr has larger ions compared to LiF, leading to lower lattice energy. - The expected order should be: \[ \text{MgO} > \text{LiF} > \text{KBr} \] - This order is correct. - **Option B**: Sodium fluoride (NaF), magnesium oxide (MgO), strontium chloride (SrCl2), titanium carbide (TiC) - Charges: Na (+1), F (-1); Mg (+2), O (-2); Sr (+2), Cl (-1); Ti (+4), C (-4). - As we move from NaF to TiC, the charges increase, leading to an increase in lattice energy. - Therefore, the expected order should be: \[ \text{TiC} > \text{MgO} > \text{SrCl2} > \text{NaF} \] - This order is correct. - **Option A**: Aluminum oxide (Al2O3), magnesium oxide (MgO), sodium oxide (Na2O) - Charges: Al (+3), O (-2); Mg (+2), O (-2); Na (+1), O (-2). - The charge on Al2O3 is higher than that of MgO and Na2O, leading to higher lattice energy. - The expected order should be: \[ \text{Al2O3} > \text{MgO} > \text{Na2O} \] - This order is correct. 3. **Identifying the Incorrect Order**: - After analyzing all options, we find that all orders presented are correct based on the principles of lattice energy. However, the question asks for the incorrect order. - Since all options are correct, we conclude that the question may have been misleading or incorrectly framed. ### Conclusion: The incorrect order of lattice energy is not explicitly provided in the options, as all analyzed orders are consistent with the principles of lattice energy.

To determine which order of lattice energy (L.E.) is incorrect, we need to analyze the given compounds based on the charges of their ions and their ionic sizes. Lattice energy is influenced by two main factors: the charge of the ions and the distance between them (interionic distance). ### Step-by-Step Solution: 1. **Understanding Lattice Energy**: - Lattice energy is directly proportional to the charge of the ions and inversely proportional to the distance between them. - Higher charges lead to higher lattice energy, while larger ionic sizes (greater interionic distance) lead to lower lattice energy. ...
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Knowledge Check

  • Which of the following orders is not correct for the decreasing order of acidic character ?

    A
    `CH_(3)CH_(2)CH(Cl)COOH gt CH_(3)CH(Cl)CH_(2)COOH gt CH_(2)(Cl)CH_(2)CH_(2)COOH gt CH_(3) CH_(2)CH_(2)COOH`
    B
    `ICH_(2)COOH gt BrCH_(2)COOH gt ClCH_(2)COOH bt FCH_(2)COOH`
    C
    `C Cl_(3)COOH gt CHCl_(2)COOH gt CH_(2)ClCOOH gt CH_(3)COOH`
    D
    `HCOOH gt CH_(3)COOH gt C_(2)H_(5)COOH gt (CH_(3))_(2)CHCOOH`
  • ALLEN-INORGANIC CHEMISTRY-s-BLOCK ELEMENTS
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    2. Which of the following compounds has ionic bond. pi-bond, co-ordinate...

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    3. Which shows the highest lattice energy ?

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    4. Melting point order is not correct is :-

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    5. In which of the following cases the covalent character and the mpt ord...

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    6. Which of the following is correct statement ? (a) AlCl(3) is conduct...

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    7. The pair with more ionic nature among lithium halides :-

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    8. Strongest reducing agent among alkali metals and alkaline earth metals...

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    9. Least mobile ion is

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    10. Choose the compounds of maximum and minimum ionic character from LiCl,...

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    11. Which of the following will be most covalent :-

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    12. Which of the following is not a correct order of solubility in water :...

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    13. Which of the following is maximum soluble in organic solvent :-

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    14. Among the following group-I carbonate having highest solubility ?

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    15. Alkaline earth metal carbonates are decomposed on heating and produce ...

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    16. Which of the following bicarbonate can exist in solid state :-

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    17. Which of the following on thermal decomposition yields a basic as well...

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    18. Which of the following equlibria would have highest and lowest value o...

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