Home
Class 12
CHEMISTRY
CH(3)CH(2)CH(2)CONH(2)overset(Br(2)//KOH...

`CH_(3)CH_(2)CH_(2)CONH_(2)overset(Br_(2)//KOH)to`Product
The organic product of above reaction is.

A

`CH_(3)CH_(2)CH_(2)NH_(2)`

B

`CH_(3)underset(CH_(2))underset(|)(CH)CH_(3)`

C

`CH_(3)CH_(2)CH_(2)CH_(2)NH_(2)`

D

`CH_(3)CH_(2)underset(NH_(2))underset(|)(C)HCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction of butanamide (CH₃CH₂CH₂CONH₂) with bromine (Br₂) in the presence of potassium hydroxide (KOH). This reaction is known as the Hofmann bromamide degradation reaction. ### Step-by-Step Solution: 1. **Identify the Reactant**: The reactant is butanamide, which has the structure CH₃CH₂CH₂CONH₂. 2. **Understand the Reaction**: The Hofmann bromamide degradation involves the treatment of an amide with bromine and a strong base (KOH). The general reaction leads to the formation of a primary amine and the loss of one carbon atom from the carbon chain. 3. **Reaction Mechanism**: - The amide group (C=O and NH₂) reacts with Br₂ and KOH. - The nitrogen atom in the amide group will rearrange, and one carbon atom will be eliminated as carbon dioxide (CO₂). - The remaining structure after the elimination will be a primary amine. 4. **Determine the Product**: - In this case, the butanamide (4 carbon atoms) will lose one carbon atom during the reaction. - The remaining structure will be propanamine (CH₃CH₂CH₂NH₂), which has 3 carbon atoms. 5. **Final Product**: The final product of the reaction is propanamine (CH₃CH₂CH₂NH₂). ### Conclusion: The organic product of the reaction between butanamide and bromine in the presence of KOH is propanamine.

To solve the problem, we need to analyze the reaction of butanamide (CH₃CH₂CH₂CONH₂) with bromine (Br₂) in the presence of potassium hydroxide (KOH). This reaction is known as the Hofmann bromamide degradation reaction. ### Step-by-Step Solution: 1. **Identify the Reactant**: The reactant is butanamide, which has the structure CH₃CH₂CH₂CONH₂. 2. **Understand the Reaction**: ...
Promotional Banner

Similar Questions

Explore conceptually related problems

CH_(3)CONH_(2) overset(H_(3)O^(+))rarr Product is :

CH_(3)-C-=CHunderset(dil.H_(2)SO_(4))overset(HgSO_(4))(to) product Product of the above reaction is

CH_(3)CH_(2)CONH_(2)underset(Br_(2))overset(NaOH)rarrA Aqueous solution of A

CH_(3) CH_(2)Cl+Ag_(2)O overset(Delta)to Product . Product formed in the reaction is

CH_(3)-overset(CH_(2)CH_(3))overset(|)(CH)CH=CHCH_(3)overset(H_(3)O^(+))rarr find the product of the reaction .

CH_(3)CH_(2)COOHunderset("Red P")overset(Br_(2))tooverset(NH_(3))toY Y in the above reaction is