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C(6)H(5)CHO+CH(3)COOCOCH(3)underset(Delt...

`C_(6)H_(5)CHO+CH_(3)COOCOCH_(3)underset(Delta)overset(CH_(3)COONa)to` products
If one product of above reaction is `C_(6)H_(5)-CH=CH-COOH` the other organic product (side product) is

A

`CH_(3)CH_(2)OH`

B

`C_(6)H_(5)COOH`

C

`CH_(3)CHO`

D

`C_(6)H_(5)-CH=CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the reaction between benzaldehyde (C₆H₅CHO) and acetic anhydride (CH₃COOCOCH₃) in the presence of sodium acetate (CH₃COONa) under heating conditions. The main product is known to be cinnamic acid (C₆H₅-CH=CH-COOH), and we need to identify the other organic product (side product) of this reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are benzaldehyde (C₆H₅CHO) and acetic anhydride (CH₃COOCOCH₃). - Sodium acetate (CH₃COONa) acts as a catalyst in this reaction. 2. **Understand the Reaction Type**: - This is a condensation reaction, specifically a Novenegel reaction, where two molecules combine with the elimination of a small molecule, which in this case is water (H₂O). 3. **Reaction Mechanism**: - When benzaldehyde reacts with acetic anhydride, a nucleophilic attack occurs. The carbonyl carbon of acetic anhydride is electrophilic and can be attacked by the nucleophilic benzaldehyde. - This leads to the formation of a β-keto acid intermediate. 4. **Elimination of Water**: - During the reaction, a molecule of water is eliminated. The reaction can be summarized as: \[ C₆H₅CHO + CH₃COOCOCH₃ \rightarrow C₆H₅-CH=CH-COOH + H₂O + CH₃COOH \] - Here, the main product is cinnamic acid (C₆H₅-CH=CH-COOH), and the side product is acetic acid (CH₃COOH). 5. **Final Products**: - The two products formed from this reaction are: - Cinnamic acid (C₆H₅-CH=CH-COOH) - Acetic acid (CH₃COOH) ### Conclusion: The other organic product (side product) of the reaction is **acetic acid (CH₃COOH)**.

To solve the given question, we need to analyze the reaction between benzaldehyde (C₆H₅CHO) and acetic anhydride (CH₃COOCOCH₃) in the presence of sodium acetate (CH₃COONa) under heating conditions. The main product is known to be cinnamic acid (C₆H₅-CH=CH-COOH), and we need to identify the other organic product (side product) of this reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are benzaldehyde (C₆H₅CHO) and acetic anhydride (CH₃COOCOCH₃). - Sodium acetate (CH₃COONa) acts as a catalyst in this reaction. ...
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