Home
Class 12
CHEMISTRY
Zn+conc.HNO(3) rarr Zn(NO(3))(2)+X+H(2)O...

`Zn+conc.HNO_(3) rarr Zn(NO_(3))_(2)+X+H_(2)O`
`Zn+dil.HNO_(3) rarr Zn(NO_(3))_(2)+Y+H_(2)O`
Compounds X and Y are respectively:

A

`N_(2)O, NO`

B

`NO_(2), N_(2)O`

C

`N_(2)O,NO_(2)`

D

`NO_(2),NO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reactions of zinc (Zn) with concentrated and dilute nitric acid (HNO3) and identify the products formed in each case. ### Step 1: Reaction of Zinc with Concentrated HNO3 When zinc reacts with concentrated nitric acid, it acts as a strong oxidizing agent. The reaction can be represented as: \[ \text{Zn} + \text{conc. HNO}_3 \rightarrow \text{Zn(NO}_3\text{)}_2 + \text{X} + \text{H}_2\text{O} \] In this reaction, zinc is oxidized, and the nitrogen in nitric acid is reduced to nitrogen dioxide (NO2). The balanced equation for this reaction is: \[ \text{4 Zn} + \text{10 HNO}_3 \rightarrow \text{4 Zn(NO}_3\text{)}_2 + \text{2 NO}_2 + \text{5 H}_2\text{O} \] Thus, the product X formed in this reaction is nitrogen dioxide (NO2). ### Step 2: Reaction of Zinc with Dilute HNO3 Now, when zinc reacts with dilute nitric acid, the reaction is milder, and the nitrogen in nitric acid is reduced to a lower oxidation state. The reaction can be represented as: \[ \text{Zn} + \text{dil. HNO}_3 \rightarrow \text{Zn(NO}_3\text{)}_2 + \text{Y} + \text{H}_2\text{O} \] In this case, the nitrogen is reduced to nitrous oxide (N2O). The balanced equation for this reaction is: \[ \text{Zn} + \text{4 HNO}_3 \rightarrow \text{Zn(NO}_3\text{)}_2 + \text{2 N}_2\text{O} + \text{2 H}_2\text{O} \] Thus, the product Y formed in this reaction is nitrous oxide (N2O). ### Conclusion From the above analysis, we can conclude that: - Compound X (from the reaction with concentrated HNO3) is NO2. - Compound Y (from the reaction with dilute HNO3) is N2O. Therefore, the answer is: - X = NO2 - Y = N2O

To solve the question, we need to analyze the reactions of zinc (Zn) with concentrated and dilute nitric acid (HNO3) and identify the products formed in each case. ### Step 1: Reaction of Zinc with Concentrated HNO3 When zinc reacts with concentrated nitric acid, it acts as a strong oxidizing agent. The reaction can be represented as: \[ \text{Zn} + \text{conc. HNO}_3 \rightarrow \text{Zn(NO}_3\text{)}_2 + \text{X} + \text{H}_2\text{O} \] ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Complete the given equations: (i) Cu + 8 HNO_(3) rarr 3 Cu(NO_(3))_(2) + overset (W)......+ 4H_(2)O (ii) 4Zn + 10HNO_(3) rarr 4Zn(NO_(3))_(2) + 5H_(2)O + overset(X).... (iii) l2 + 10 HNO_(3)rarr overset(Y)....+10 NO_(2) + 4H_(2)O

PbO_(2) ↓+HNO_(3)("Conc.") to Pb(NO_(3))_(2)+H_(2)O+[O]

PbO_(2)↓+HNO_(3)("Conc.") to Pb(NO_(3))_(2)+H_(2)O+[O]

Balance the equation Mg+ HNO_(3) to Mg(NO_(3))_(2) + N_(2)O + H_(2)O

The ratio of coefficient of HNO_(3), Fe(NO_(3))_(2) and NH_(4)NO_(3) in the following redox reaction Fe + HNO_(3) rarr Fe (NO_(3))_(2) + NH_(4)NO_(3) + H_(2)O are respectively

Consider the equations given below and find the sum of x, y and z. (i) Mg+underset("(very dilute)")(xHNO_(3))(5%)rarrMg(NO_(3))_(2)+H_(2) (ii) Cu+underset("(dil.)")(yHNO_(3))rarr 3Cu(NO_(3))_(2)+2NO+4H_(2)O (iii) I_(2)+zHNO_(3)rarr 2HIO_(3)+10NO_(2)+4H_(2)O

For the redox reaction Zn+NO_(3)^(-)rarr Zn^(2+)+NH_(4)^(-) is basic medium, coefficients of Zn, NO_(3)^(-) and OH^(-) in the balanced equation respectively are :

Copper (Cu) and (Zn) react differently with HNO_(3) as follows: Cu + 4H^(o+) (aq) + 2NO_(3)^(ɵ) (aq) rarr 2NO_(2)(g) _ Cu^(2+) + 2H_(2)O 4Zn +10 H^(o+) (aq) + 2NO_(3)^(ɵ) (aq) rarr NH_(4)^(o+) + 4Zn^(2+) + 3H_(2)O What volume of NO_(2) gas at 27^(@)C and 1.0 atm pressure would be produced? if given 2 M HNO_(3) react with 10 g of a brass ( 90 % Cu 10% Zn) according to the above equation.

Copper (Cu) and (Zn) react differently with HNO_(3) as follows: Cu + 4H^(o+) (aq) + 2NO_(3)^(ɵ) (aq) rarr 2NO_(2)(g) _ Cu^(2+) + 2H_(2)O 4Zn +10 H^(o+) (aq) + 2NO_(3)^(ɵ) (aq) rarr NH_(4)^(o+) + 4Zn^(2+) + 3H_(2)O What volume of 2.0 M HNO_(3) would react with 10.0g of a brass (90.% Cu, 10.0% Zn) according to the above equation?

What is the n-factor for HNO_(2) in the reaction 3HNO_(2)rarr HNO_(3)+2NO+H_(2)O ?