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CH(3) - overset(O)overset(||)C - H + CH(...

`CH_(3) - overset(O)overset(||)C - H + CH_(3) = CH_(2) - Cl underset("heat")overset(PPH_(3)//LiCl)rarr 'X' , X` will be

A

B

C

`CH_(3) - CH - O - CH_(3)`

D

`CH_(3)= overset(OH)overset(|)C - CH_(3) - CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the reaction step-by-step. The reaction involves acetaldehyde (CH₃CHO) reacting with vinyl chloride (CH₂=CHCl) in the presence of a reducing agent (PPh₃) and heat. ### Step-by-Step Solution: 1. **Identify the Reactants**: - We have acetaldehyde: CH₃CHO - We have vinyl chloride: CH₂=CHCl 2. **Recognize the Reaction Type**: - The reaction is a nucleophilic addition where the carbonyl carbon of acetaldehyde acts as an electrophile and the double bond of vinyl chloride acts as a nucleophile. 3. **Nucleophilic Attack**: - The nucleophile (vinyl chloride) attacks the electrophilic carbonyl carbon of acetaldehyde. This leads to the formation of a tetrahedral intermediate. 4. **Formation of the Intermediate**: - The tetrahedral intermediate can be represented as: \[ CH₃C(OH)(CH₂=CHCl) \] - Here, the chlorine atom (Cl) is a good leaving group, and it will leave the intermediate. 5. **Elimination of Chlorine**: - The leaving of Cl⁻ will lead to the formation of an alkene. The resulting compound after the elimination of Cl will be: \[ CH₃C(CH₂=CH)O \] 6. **Reduction with PPh₃**: - The presence of PPh₃ indicates that we will reduce the carbonyl group (C=O) to an alcohol (C-OH). Thus, we will convert the carbonyl to an alcohol: \[ CH₃C(CH₂=CH)OH \] 7. **Tautomerization**: - The alcohol can undergo tautomerization, where the hydrogen from the alcohol group can shift to the adjacent carbon, resulting in the formation of an enol: \[ CH₂=CHC(OH)CH₃ \] 8. **Final Product**: - The final product 'X' can be represented as: \[ CH₂=CHC(OH)CH₃ \] - This compound is 3-buten-2-ol. ### Conclusion: The product 'X' formed from the reaction is 3-buten-2-ol.

To solve the given question, we need to analyze the reaction step-by-step. The reaction involves acetaldehyde (CH₃CHO) reacting with vinyl chloride (CH₂=CHCl) in the presence of a reducing agent (PPh₃) and heat. ### Step-by-Step Solution: 1. **Identify the Reactants**: - We have acetaldehyde: CH₃CHO - We have vinyl chloride: CH₂=CHCl ...
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