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Which of the following is low spin to st...

Which of the following is low spin to strong field ligands

A

`d_(xy)^(2)d_(zx)^(2)d_(yz)^(1)`

B

`d_(xy)^(2), d_(yz)^(1), d_(zx)^(1), d_(x^(2)y^(2))^(1), d_(z^(2))^(1)`

C

`d_(xy)^(2), d_(yz)^(1), d_(zx)^(1), d_(z^(2))^(1)`

D

`d_(x^(2)^(1) - y_(2)), d_(z^(2))^(1)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the following is a low spin to strong field ligand, we need to understand the concepts of low spin and strong field ligands, particularly in the context of octahedral complexes. ### Step-by-Step Solution: 1. **Understanding Low Spin and Strong Field Ligands**: - Low spin complexes are typically formed by strong field ligands. Strong field ligands cause a larger splitting of the d-orbitals in transition metal complexes, leading to a preference for pairing of electrons in the lower energy orbitals (T2G) before occupying the higher energy orbitals (EG). 2. **Octahedral Complexes**: - In octahedral complexes, the d-orbitals split into two energy levels: the lower energy level (T2G) and the higher energy level (EG). - T2G level consists of the orbitals dxy, dyz, and dxz, while the EG level consists of the orbitals dx²-y² and dz². 3. **Filling of Electrons**: - In a low spin complex, electrons will fill the T2G level first and pair up before occupying the EG level. This results in fewer unpaired electrons. - For example, if we have a d6 configuration in a strong field ligand, the electrons would fill as follows: T2G (2 electrons in dxy, 2 in dyz, and 2 in dxz) and none in EG. 4. **Identifying Strong Field Ligands**: - Common strong field ligands include CN⁻ (cyanide), CO (carbon monoxide), and NH₃ (ammonia). Weak field ligands include H₂O (water) and halides (F⁻, Cl⁻, etc.). - To identify the correct option, we need to check which ligand is known to be a strong field ligand. 5. **Evaluating the Options**: - Review the provided options (not listed in the question, but assumed to be present). - Identify which ligand corresponds to a strong field ligand based on the knowledge of ligand field theory. 6. **Conclusion**: - After evaluating the options, we conclude that the correct answer is the ligand that is classified as a strong field ligand, which will lead to a low spin configuration.

To determine which of the following is a low spin to strong field ligand, we need to understand the concepts of low spin and strong field ligands, particularly in the context of octahedral complexes. ### Step-by-Step Solution: 1. **Understanding Low Spin and Strong Field Ligands**: - Low spin complexes are typically formed by strong field ligands. Strong field ligands cause a larger splitting of the d-orbitals in transition metal complexes, leading to a preference for pairing of electrons in the lower energy orbitals (T2G) before occupying the higher energy orbitals (EG). 2. **Octahedral Complexes**: ...
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