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H(2)C=CH-CH(2)-overset(O)overset(||)C-H ...

`H_(2)C=CH-CH_(2)-overset(O)overset(||)C-H overset("Reagent")rarr`
`CH_(2)-CH_(2)-CH_(2)-CH_(2)-OH`
Appropriate reagent for above conversion will be

A

Metal `+ H_(2)`

B

`LiAlH_(4)`

C

`NaBH_(4)`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to identify the appropriate reagent for the conversion of the compound with a double bond and an aldehyde group to the desired alcohol product. Here’s a step-by-step breakdown of the solution: ### Step-by-Step Solution: 1. **Identify the Reactants and Products:** - The reactant is an alkene with a terminal aldehyde: H₂C=CH-CH₂-CHO. - The product is a straight-chain alcohol: CH₂-CH₂-CH₂-CH₂-OH. 2. **Understand the Reaction Type:** - The reaction involves the reduction of an aldehyde (CHO) to an alcohol (OH) and the alkene (C=C) to a saturated alkane (C-C). 3. **Select the Reagents:** - For the reduction of aldehydes and alkenes, we can use: - Metal + H₂ (e.g., hydrogenation using a catalyst like Pd, Pt, or Ni) - Lithium Aluminium Hydride (LiAlH₄) - Sodium Borohydride (NaBH₄) 4. **Analyze the Effects of Each Reagent:** - **Metal + H₂:** This reagent will reduce both the double bond (alkene) and the aldehyde group, converting the entire structure to a saturated alcohol. - **Lithium Aluminium Hydride (LiAlH₄):** This reagent selectively reduces the aldehyde to an alcohol without affecting the double bond. - **Sodium Borohydride (NaBH₄):** Similar to LiAlH₄, it will reduce the aldehyde to an alcohol but will not reduce the alkene. 5. **Determine the Final Product:** - The desired product is CH₂-CH₂-CH₂-CH₂-OH, which indicates that both the double bond and the aldehyde need to be reduced. - Therefore, the most suitable reagent for this conversion is **Metal + H₂**, as it will reduce both functional groups. ### Final Answer: The appropriate reagent for the conversion is **Metal + H₂**. ---

To solve the given question, we need to identify the appropriate reagent for the conversion of the compound with a double bond and an aldehyde group to the desired alcohol product. Here’s a step-by-step breakdown of the solution: ### Step-by-Step Solution: 1. **Identify the Reactants and Products:** - The reactant is an alkene with a terminal aldehyde: H₂C=CH-CH₂-CHO. - The product is a straight-chain alcohol: CH₂-CH₂-CH₂-CH₂-OH. ...
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