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Which of the following statement is not ...

Which of the following statement is not true regarding `B_(2)H_(6)` ?

A

It reacts with `NaH` to form `NaBH_(4)`

B

It is inflammable gas

C

It does not contain four equal `B - H` bonds

D

it reacts with Lewis base to form adduct

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is not true regarding diborane (B₂H₆), we will analyze each option provided. ### Step-by-Step Solution: 1. **Analyze Option A: "It reacts with NaH to form NaBH₄."** - Diborane (B₂H₆) can react with sodium hydride (NaH) to produce sodium borohydride (NaBH₄). The reaction can be represented as: \[ B_2H_6 + 2 NaH \rightarrow 2 NaBH_4 \] - This statement is true. 2. **Analyze Option B: "It is an inflammable gas."** - Diborane is known to be highly volatile and flammable. It can ignite spontaneously in air. Therefore, this statement is also true. 3. **Analyze Option C: "It does not contain 4 equal BH bonds."** - The structure of diborane (B₂H₆) consists of two boron atoms and six hydrogen atoms. It has a unique bonding arrangement where there are two bridging hydrogen atoms and four terminal hydrogen atoms. The bonding involves 3-center 2-electron bonds, which means that not all bonds are equivalent. Thus, the statement that it does not contain 4 equal BH bonds is true. 4. **Analyze Option D: "It reacts with Lewis acid to form an adduct."** - Diborane can react with Lewis acids, such as ammonia (NH₃), to form an adduct. The reaction can be represented as: \[ B_2H_6 + NH_3 \rightarrow [B_2H_5(NH_3)] \] - This statement is also true. ### Conclusion: After analyzing all the options, the statement that is not true is **Option C: "It does not contain 4 equal BH bonds."** This is incorrect because diborane does not have 4 equal BH bonds due to its unique bonding structure. ### Final Answer: The statement that is not true regarding B₂H₆ is **Option C: "It does not contain 4 equal BH bonds."**
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