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Find out no of compounds that gives posi...

Find out no of compounds that gives positive iodoform test (either in cold or hot condition)
(A) `H_(3)C-underset(O)underset(||)(C)-CH_(2)-CH_(3)`
(B) `I_(3)C-underset(O)underset(||)(C)-CH_(2)-CH_(3)`
(C) `CH_(3)-underset(OH)underset(|)(C)-CH_(2)CH_(3)`
(D) `CH_(2) l -underset(OH)underset(|)(CH)-CH_(2)CH_(3)`
(E) `CH_(3)CH_(2)OH`

Text Solution

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The correct Answer is:
To determine the number of compounds that give a positive iodoform test, we need to analyze each compound based on the criteria for the iodoform test. The iodoform test is positive for compounds that have a methyl ketone group (RCOCH3) or a secondary alcohol that can be oxidized to a methyl ketone. ### Step-by-Step Solution: 1. **Analyze Compound A: `H₃C-(O=)(C)-CH₂-CH₃`** - This is a ketone (specifically, a methyl ketone). - It has 3 alpha hydrogens (from the CH₃ group). - **Conclusion**: This compound gives a positive iodoform test. 2. **Analyze Compound B: `I₃C-(O=)(C)-CH₂-CH₃`** - This is also a ketone, but it has three iodine atoms attached to the methyl group. - It can still undergo the iodoform reaction since it can be cleaved to form iodoform (CHI₃). - **Conclusion**: This compound gives a positive iodoform test. 3. **Analyze Compound C: `CH₃-(OH)-(C)-CH₂-CH₃`** - This is a secondary alcohol. - Upon oxidation, it can be converted to a methyl ketone (specifically, to a ketone with 3 alpha hydrogens). - **Conclusion**: This compound gives a positive iodoform test. 4. **Analyze Compound D: `CH₂Cl-(OH)-(C)-CH₂-CH₃`** - This is also a secondary alcohol, but it has only 2 alpha hydrogens (the CH₂ group). - It cannot be oxidized to form a methyl ketone. - **Conclusion**: This compound does NOT give a positive iodoform test. 5. **Analyze Compound E: `CH₃CH₂OH`** - This is a primary alcohol. - Upon oxidation, it can be converted to acetaldehyde (which has 3 alpha hydrogens). - **Conclusion**: This compound gives a positive iodoform test. ### Final Count of Compounds: - Positive iodoform test: A, B, C, E - Negative iodoform test: D Thus, the total number of compounds that give a positive iodoform test is **4** (A, B, C, and E). ### Summary of Results: - **Compounds giving a positive iodoform test**: A, B, C, E - **Total**: 4 compounds

To determine the number of compounds that give a positive iodoform test, we need to analyze each compound based on the criteria for the iodoform test. The iodoform test is positive for compounds that have a methyl ketone group (RCOCH3) or a secondary alcohol that can be oxidized to a methyl ketone. ### Step-by-Step Solution: 1. **Analyze Compound A: `H₃C-(O=)(C)-CH₂-CH₃`** - This is a ketone (specifically, a methyl ketone). - It has 3 alpha hydrogens (from the CH₃ group). - **Conclusion**: This compound gives a positive iodoform test. ...
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