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Find out no of correct statements (A) ...

Find out no of correct statements
(A) `N_(2)gtN` (Ist ionization Energy)
(B) `O_(2)gtO` (Ist Ionization Energy)
(C) `H_(2)gtH` (Ist ionization Energy)
(D) `N_(2)^(+)gtN_(2)^(-)` (Stability)
(E) `O_(2)gtO` (Ist Electron affinity)
(G) `Na_(2)CO_(3)gtLi_(2)CO_(3)` (Thermal stability)
(H) NO of co-ordinate bond in `P_(4)O_(10)` is `4`
(I) No of `pi` bond in `P_(4)O_(8)` is 2

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of correct statements from the provided options, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement (A): `N_(2) > N` (1st Ionization Energy)** - The last electron in `N2` is in a bonding molecular orbital, while in `N` it is in a pure p orbital. Bonding molecular orbitals are more stable than pure p orbitals. - **Conclusion**: This statement is **correct**. 2. **Statement (B): `O_(2) > O` (1st Ionization Energy)** - The last electron in `O2` is in an anti-bonding molecular orbital, while in `O` it is in a pure p orbital. Anti-bonding orbitals are less stable than pure p orbitals. - **Conclusion**: This statement is **incorrect**. 3. **Statement (C): `H_(2) > H` (1st Ionization Energy)** - Both electrons in `H2` are in bonding molecular orbitals, while in `H`, the electron is in a pure s orbital. Bonding orbitals are more stable than pure s orbitals. - **Conclusion**: This statement is **correct**. 4. **Statement (D): `N_(2)^(+) > N_(2)^(-)` (Stability)** - `N2^+` and `N2^-` have the same bond order, but the last electron in `N2^+` is in a bonding molecular orbital, while in `N2^-` it is in an anti-bonding molecular orbital. Therefore, `N2^+` is more stable. - **Conclusion**: This statement is **correct**. 5. **Statement (E): `O_(2) > O` (1st Electron Affinity)** - `O2` has a complete octet, while `O` does not. Therefore, the electron affinity of `O2` is less than that of `O`. - **Conclusion**: This statement is **incorrect**. 6. **Statement (G): `Na_(2)CO_(3) > Li_(2)CO_(3)` (Thermal Stability)** - As we move down the group in the periodic table, the metallic character increases, which in turn increases the thermal stability of the compounds. - **Conclusion**: This statement is **correct**. 7. **Statement (H): Number of coordinate bonds in `P_(4)O_(10)` is `4`** - The structure of `P4O10` shows that there are indeed 4 coordinate bonds. - **Conclusion**: This statement is **correct**. 8. **Statement (I): Number of `pi` bonds in `P_(4)O_(8)` is `2`** - The structure of `P4O8` shows that there are 2 pi bonds. - **Conclusion**: This statement is **correct**. ### Summary of Correct Statements: - Correct Statements: A, C, D, G, H, I - Incorrect Statements: B, E ### Total Number of Correct Statements: - There are **6 correct statements**.

To determine the number of correct statements from the provided options, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement (A): `N_(2) > N` (1st Ionization Energy)** - The last electron in `N2` is in a bonding molecular orbital, while in `N` it is in a pure p orbital. Bonding molecular orbitals are more stable than pure p orbitals. - **Conclusion**: This statement is **correct**. ...
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