Home
Class 12
CHEMISTRY
Co forms dinuclear complex with a sigma ...

Co forms dinuclear complex with a sigma bond with in two Cop atoms. Consider that metal carbonyls follows EAN rule. the complex can be written as `CO_(2)(CO)_(x)`. Find the value of `x`?

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of \( x \) in the dinuclear complex \( \text{Co}_2(\text{CO})_x \) using the Effective Atomic Number (EAN) rule, we can follow these steps: ### Step 1: Understand the EAN Rule The EAN rule states that the effective atomic number of a metal in a complex can be calculated using the formula: \[ \text{EAN} = Z - y + 2x \] where: - \( Z \) is the atomic number of the metal, - \( y \) is the oxidation state of the metal, - \( x \) is the number of ligands. ### Step 2: Determine the Atomic Number of Cobalt Cobalt (Co) has an atomic number of 27. ### Step 3: Identify the Oxidation State of Cobalt In the dinuclear complex \( \text{Co}_2(\text{CO})_x \), the oxidation state of cobalt can be assumed to be 0 because CO is a neutral ligand. Therefore, \( y = 0 \). ### Step 4: Calculate the EAN for Cobalt According to the problem, the EAN for cobalt in this complex is given as 36. ### Step 5: Substitute Values into the EAN Formula Substituting the known values into the EAN formula: \[ 36 = 27 - 0 + 2 \left(\frac{x}{2}\right) \] Here, \( \frac{x}{2} \) accounts for the fact that there are two cobalt atoms in the complex. ### Step 6: Simplify the Equation The equation simplifies to: \[ 36 = 27 + x \] ### Step 7: Solve for \( x \) Now, we can solve for \( x \): \[ x = 36 - 27 = 9 \] ### Step 8: Conclusion Thus, the value of \( x \) is 9. ### Final Answer The value of \( x \) is \( 9 \). ---

To find the value of \( x \) in the dinuclear complex \( \text{Co}_2(\text{CO})_x \) using the Effective Atomic Number (EAN) rule, we can follow these steps: ### Step 1: Understand the EAN Rule The EAN rule states that the effective atomic number of a metal in a complex can be calculated using the formula: \[ \text{EAN} = Z - y + 2x \] where: ...
Promotional Banner

Similar Questions

Explore conceptually related problems

With which of the following metals, CO forms a volatile carbonyl complex?

Which of the given metal ion form high tendency to complex with CO ?

In the complex Fe(CO)_(x) , the value of x is if its EAN is 36.

A covalent bond will be formed by the overlapping of atomic orbitals having single electron of opposite spin, according to the overlapping of atomic orbitals the covalent bond may be of two types : (i) Sigma bond (sigma) " " (ii) Pi bond (pi) Sigma bond is stronger bond than the Pi-bond. If atomic orbitals overlap about the nuclear axis then sigma bond is formed but when atomic orbitals overlap sideway then Pi-bond is formed. The correct order of increasing C-O bond length of CO,CO_(3)^(2-),CO_(2) is :

Barium ion , CN^(-) and Co^(2+) form an ionic complex . If that complex is supposed to be 75% ionised in water with van't Hoff factor 'i' equal to four , then the coordination number of Co^(2+) in the complex can be :

Find the coordination number and oxidation state of the metal in the following complex compounds. [Co(en)_3]^(3+)

Which of the following is true for the complex Co(NO_(2) )(Cl)_(2) .5NH_(3) (Co is in + 3 oxidation state)

If 4cos^(2)x=3 and x is an acute angle, find the value of : cos3x

Consider the following carbonyl complex compounds. (i) Mo(CO)_(x) (ii) H_(y)[Cr(CO)_(5)] and (iii) Co_(2)(CO)_(z) Then calculate value of |x+y-z| .

EAN of a metal carbonyl M(CO)_(x) is 36. If atomic number of metal M is 26, what is the value of x?