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On treated with dilute H(2)SO(4), a salt...

On treated with dilute `H_(2)SO_(4)`, a salt gives a gas which turns lime water milky. The salt can be

A

`NaHCO_(3)`

B

`Na_(2)CO_(3)`

C

`Na_(2)SO_(3)`

D

`NaNO_(2)`

Text Solution

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The correct Answer is:
To solve the question, we need to identify the salt that, when treated with dilute H₂SO₄, produces a gas that turns lime water milky. Lime water is a solution of calcium hydroxide (Ca(OH)₂), and it turns milky when carbon dioxide (CO₂) is bubbled through it, forming calcium carbonate (CaCO₃), which is insoluble in water. ### Step-by-Step Solution: 1. **Identify the salts**: We need to consider the possible salts that could react with dilute H₂SO₄. The options given are: - A) NaHCO₃ (Sodium bicarbonate) - B) Na₂CO₃ (Sodium carbonate) - C) Na₂SO₃ (Sodium sulfite) - D) NaNO₂ (Sodium nitrite) 2. **Reactions with dilute H₂SO₄**: - **For NaHCO₃**: \[ \text{NaHCO}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + \text{H}_2\text{O} + \text{CO}_2 \] This reaction produces CO₂ gas, which will turn lime water milky. - **For Na₂CO₃**: \[ \text{Na}_2\text{CO}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + \text{H}_2\text{O} + \text{CO}_2 \] This reaction also produces CO₂ gas, which will turn lime water milky. - **For Na₂SO₃**: \[ \text{Na}_2\text{SO}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + \text{H}_2\text{O} + \text{SO}_2 \] This reaction produces SO₂ gas. SO₂ can also turn lime water milky, forming calcium sulfite (CaSO₃). - **For NaNO₂**: \[ \text{NaNO}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + \text{NO} + \text{NO}_2 + \text{H}_2\text{O} \] This reaction produces NO and NO₂ gases, which do not turn lime water milky. 3. **Conclusion**: - From the reactions above, we see that NaHCO₃, Na₂CO₃, and Na₂SO₃ produce gases (CO₂ and SO₂) that can turn lime water milky. - NaNO₂ does not produce a gas that turns lime water milky. Thus, the salts that can give a gas which turns lime water milky when treated with dilute H₂SO₄ are: - **NaHCO₃ (Sodium bicarbonate)** - **Na₂CO₃ (Sodium carbonate)** - **Na₂SO₃ (Sodium sulfite)** ### Final Answer: The salt can be **NaHCO₃, Na₂CO₃, or Na₂SO₃**.

To solve the question, we need to identify the salt that, when treated with dilute H₂SO₄, produces a gas that turns lime water milky. Lime water is a solution of calcium hydroxide (Ca(OH)₂), and it turns milky when carbon dioxide (CO₂) is bubbled through it, forming calcium carbonate (CaCO₃), which is insoluble in water. ### Step-by-Step Solution: 1. **Identify the salts**: We need to consider the possible salts that could react with dilute H₂SO₄. The options given are: - A) NaHCO₃ (Sodium bicarbonate) - B) Na₂CO₃ (Sodium carbonate) - C) Na₂SO₃ (Sodium sulfite) ...
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