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A vessel at 1000K contains CO(2)(g) at 2...

A vessel at `1000K` contains `CO_(2)(g)` at `2` atm pressure. When graphite is added the following equilibrium is established.
`CO_(2)(g)+C(s) hArr 2CO(g)`
the toal pressure at equilibrium is 3 atm. The value of `K_(p)` is

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To solve the problem, we need to determine the equilibrium constant \( K_p \) for the reaction: \[ CO_2(g) + C(s) \rightleftharpoons 2CO(g) \] Given the initial conditions and the equilibrium state, we can follow these steps: ### Step 1: Initial Conditions The vessel contains \( CO_2 \) at a pressure of 2 atm and no \( CO \) is present initially. The pressure of the solid carbon (graphite) does not affect the equilibrium expression since solids are not included in the \( K_p \) expression. ### Step 2: Change in Pressure Let \( x \) be the change in pressure of \( CO_2 \) that reacts to form \( CO \). At equilibrium, the pressures will be: - Pressure of \( CO_2 \) at equilibrium: \( 2 - x \) atm - Pressure of \( CO \) at equilibrium: \( 2x \) atm ### Step 3: Total Pressure at Equilibrium We know that the total pressure at equilibrium is 3 atm: \[ (2 - x) + 2x = 3 \] ### Step 4: Solve for \( x \) Simplifying the equation: \[ 2 - x + 2x = 3 \] \[ 2 + x = 3 \] \[ x = 1 \text{ atm} \] ### Step 5: Calculate Partial Pressures at Equilibrium Now we can find the partial pressures at equilibrium: - Pressure of \( CO_2 \): \( 2 - x = 2 - 1 = 1 \) atm - Pressure of \( CO \): \( 2x = 2 \times 1 = 2 \) atm ### Step 6: Write the Expression for \( K_p \) The expression for \( K_p \) for the reaction is given by: \[ K_p = \frac{(P_{CO})^2}{P_{CO_2}} \] Substituting the equilibrium pressures: \[ K_p = \frac{(2)^2}{1} = \frac{4}{1} = 4 \] ### Final Answer Thus, the value of \( K_p \) is: \[ \boxed{4} \]

To solve the problem, we need to determine the equilibrium constant \( K_p \) for the reaction: \[ CO_2(g) + C(s) \rightleftharpoons 2CO(g) \] Given the initial conditions and the equilibrium state, we can follow these steps: ...
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