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A compound of iron and chlorine (Fe) so...

A compound of iron and chlorine (Fe) soluble in water . An excess of silver nitrates was added to precipitate the chloride ion as silver chloride . If a `134.8` mg of the compound gave `304.8`mg of AgCl. What is the value of x ?

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To solve the problem, we need to determine the value of \( x \) in the compound \( \text{FeCl}_x \) based on the given data. Here are the steps to arrive at the solution: ### Step 1: Calculate the moles of AgCl formed The mass of AgCl precipitate is given as \( 304.8 \, \text{mg} \). First, we convert this mass into grams: \[ 304.8 \, \text{mg} = 304.8 \times 10^{-3} \, \text{g} = 0.3048 \, \text{g} \] Next, we need to find the number of moles of AgCl. The molar mass of AgCl is approximately \( 143.32 \, \text{g/mol} \). Using the formula for moles: \[ \text{Moles of AgCl} = \frac{\text{mass of AgCl}}{\text{molar mass of AgCl}} = \frac{0.3048 \, \text{g}}{143.32 \, \text{g/mol}} \approx 0.00212 \, \text{mol} \] ### Step 2: Relate moles of AgCl to moles of chloride ions Since each mole of AgCl corresponds to one mole of chloride ions (\( \text{Cl}^- \)), the moles of chloride ions will also be: \[ \text{Moles of Cl}^- = 0.00212 \, \text{mol} \] ### Step 3: Calculate the mass of chloride ions The mass of chloride ions can be calculated using the molar mass of chlorine, which is approximately \( 35.5 \, \text{g/mol} \): \[ \text{Mass of Cl}^- = \text{moles of Cl}^- \times \text{molar mass of Cl} = 0.00212 \, \text{mol} \times 35.5 \, \text{g/mol} \approx 0.0753 \, \text{g} = 75.3 \, \text{mg} \] ### Step 4: Set up the equation for the compound The total mass of the compound \( \text{FeCl}_x \) is given as \( 134.8 \, \text{mg} \). The mass of the compound can be expressed in terms of \( x \): \[ \text{Mass of FeCl}_x = \text{mass of Fe} + \text{mass of Cl} \] The molar mass of the compound \( \text{FeCl}_x \) can be expressed as: \[ \text{Molar mass of FeCl}_x = 56 \, \text{g/mol} + 35.5 \, \text{g/mol} \times x \] ### Step 5: Relate the mass of the compound to the mass of chloride We can express the mass of chloride in terms of the mass of the compound: \[ \text{Mass of Cl} = \frac{\text{mass of compound}}{\text{molar mass of compound}} \times x \times 35.5 \] Setting this equal to the mass of chloride we calculated: \[ 75.3 \, \text{mg} = \frac{134.8 \, \text{mg}}{56 + 35.5x} \times x \times 35.5 \] ### Step 6: Solve for \( x \) Now we can rearrange and solve for \( x \): 1. Convert all masses to grams for consistency. 2. Rearranging gives us: \[ 75.3 = \frac{134.8 \times 35.5x}{56 + 35.5x} \] 3. Cross-multiply and simplify to find \( x \). After calculations, we find \( x \approx 1.8 \). Since \( x \) must be an integer, we round it to the nearest whole number: \[ x = 2 \] ### Final Answer The value of \( x \) in the compound \( \text{FeCl}_x \) is \( 2 \), so the compound is \( \text{FeCl}_2 \). ---
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