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If lamda=c(2)[(n^(2))/(n^(2)-Z^(2))] for...

If `lamda=c_(2)[(n^(2))/(n^(2)-Z^(2))]` for Balmer series what is the value of `C_(2)`?

A

`r/(R_(H))`

B

`2/(R_(H))`

C

`2R_(H)`

D

`4R_(H)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of \( C_2 \) in the equation for the Balmer series given by \[ \lambda = C_2 \frac{n^2}{n^2 - Z^2} \] we can follow these steps: ### Step 1: Understand the Balmer Series The Balmer series corresponds to electron transitions in a hydrogen atom where the electron falls to the second energy level (n=2). The formula for the wavelength of emitted light in the Balmer series can be derived from the Rydberg formula: \[ \frac{1}{\lambda} = R_H \cdot Z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( R_H \) is the Rydberg constant for hydrogen, - \( Z \) is the atomic number (for hydrogen, \( Z = 1 \)), - \( n_1 \) is the lower energy level (for Balmer series, \( n_1 = 2 \)), - \( n_2 \) is the higher energy level (where \( n_2 \) can be 3, 4, 5, ...). ### Step 2: Substitute Values into the Rydberg Formula For the Balmer series, we set \( n_1 = 2 \): \[ \frac{1}{\lambda} = R_H \cdot Z^2 \left( \frac{1}{2^2} - \frac{1}{n_2^2} \right) \] This simplifies to: \[ \frac{1}{\lambda} = R_H \cdot Z^2 \left( \frac{1}{4} - \frac{1}{n_2^2} \right) \] ### Step 3: Rearranging the Equation Rearranging gives: \[ \lambda = \frac{1}{R_H \cdot Z^2 \left( \frac{1}{4} - \frac{1}{n_2^2} \right)} \] ### Step 4: Find a Common Denominator To combine the terms in the parentheses: \[ \frac{1}{4} - \frac{1}{n_2^2} = \frac{n_2^2 - 4}{4n_2^2} \] Thus, we have: \[ \lambda = \frac{4n_2^2}{R_H \cdot Z^2 (n_2^2 - 4)} \] ### Step 5: Compare with Given Formula Now, we compare this with the given formula: \[ \lambda = C_2 \frac{n^2}{n^2 - Z^2} \] From our derived equation, we see that: \[ C_2 = \frac{4}{R_H \cdot Z^2} \] ### Step 6: Substitute \( Z \) For hydrogen, \( Z = 1 \): \[ C_2 = \frac{4}{R_H \cdot 1^2} = \frac{4}{R_H} \] ### Step 7: Final Value of \( C_2 \) Thus, the value of \( C_2 \) is: \[ C_2 = \frac{4}{R_H} \] ### Conclusion The final answer is: \[ C_2 = \frac{4}{R_H} \]

To find the value of \( C_2 \) in the equation for the Balmer series given by \[ \lambda = C_2 \frac{n^2}{n^2 - Z^2} \] we can follow these steps: ...
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