Home
Class 12
CHEMISTRY
KF has NaCl structure. What is the dista...

KF has NaCl structure. What is the distance between `K^(+)` and `F^(-)` in KF, if the density is `1.5g cm^(-3)`?

Text Solution

Verified by Experts

Since KF has NaCl structure, i.e., `Cl^(-), F^(-)` ions are present at all six faces and all corners of the cube. Similarly, like `Na^(+)`, all `K^(+)` ions occupy the middle position of 12 edges of the cube and centre of the cube.
`a=2(r_(K^(+))+r_(F^(-)))`
or `r_(K^(+))+r_(F^(-))=(a)/(2)`
As we know
Density `(rho) = (n xx M_(m))/(N_(o)xx a^(3))`
Here, n = 4
`M_(m)=` Molar mass of `KF = (39+19)gm = 58 gm`
`rho = (4xx58)/(6.023xx10^(23)xx a^(3))`
or `a^(3)=(4xx58)/(6.023xx10^(23)xx2.48)`
or `a = 5.37xx10^(-8)cm`
`= 5.37 Å`
`therefore r_(K^(+))+r_(F^(-))=2.685 Å`
Promotional Banner

Similar Questions

Explore conceptually related problems

KF has NaCl structure. What is the distance between K^(+) and F^(-) in KF, if its density is 2.48 g cm^(-3) ?

KF and NaCl struture. If the distance between K ^(+) and F^(-) is 269 pm, find the denisty of KF ( N_(A) = 6.02 xx 10^(23) "mol"^(-1) a atomic mass of copper = 63.5

The distance between Na^+ and Cl^- ions in NaCl with a density 3.165 g cm^(-3) is

Potassium fluoride has NaCI type structure .What is the distance between K' and F ions if cell edge is a cm?

What is the distance between Na^(+) and Cl^(-) ions in NaCl crystal if its density is 2.165g cm^(-3) ? NaCl crystallizes in fcc lattice.

A metal X has a BCC structure with nearest neighbor distance 365.9 pm. What is metal X if its density is 1.0016 g cm^(-3) ?

KF crystallizes in the rock salt type structure. If the radius of K^+ ion is 132 pm and that of F^- ion is 135 pm. (i)What is the shortest distance between K^+ and F^- ions ? (ii)What is the edge length of the unit cell ? (iii)What is closest K-K distance ?

CsCl has cubic structure. Its density is 3.99 g cm^(-3) . What is the distance between Cs^(o+) and Cl^(Θ) ions? (Atomic mass of Cs = 133 )

What is the molality of a semimolar NaCl solution if the density of the solution is 1.16 g cm^(-3) ?

Aluminium has fcc structure. The length of the unit cell is 409 pm. If the density of the metal is 2.7 g" " cm^(-3) , the molar mass of Al atom is