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Additionof CdCl2 to AgCl yields solid so...

Additionof `CdCl_2` to AgCl yields solid solutions , where the divalent cations `Cd^(2+)` occupy the `Ag^+` sites . Which one of the following statement in true ?

A

The no of cationic vacancies is equal to that of divalent ions added.

B

The no. of cationic vacancies is one half of the no. of that of divalent ions added.

C

The no. of anionic vacancies is equal in no. to that of divalent ions added.

D

No cationic or anionic vacancies are produced.

Text Solution

Verified by Experts

The correct Answer is:
A
To maintain the electrical neutrality, the no. of cationic vacancies is equal to the no. of divalent ions added.
Hence (A) is the correct answer.
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