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An unknown metal is found to have a spec...

An unknown metal is found to have a specific gravity of 10.2 at `25^(@)C`. It is found to crystallize in a body centered cubic lattice with a unit cell edge length of `3.147 Å`. Calculate the atomic weight.

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To calculate the atomic weight of the unknown metal, we can follow these steps: ### Step 1: Understand the Given Data - Specific Gravity (SG) = 10.2 - Density (ρ) = 10.2 g/cm³ (since SG is the ratio of the density of a substance to the density of water) - Unit cell type = Body-Centered Cubic (BCC) - Unit cell edge length (a) = 3.147 Å = 3.147 × 10⁻⁸ cm (conversion from angstroms to centimeters) ### Step 2: Calculate the Volume of the Unit Cell The volume (V) of the cubic unit cell can be calculated using the formula: \[ V = a^3 \] Substituting the value of a: \[ V = (3.147 \times 10^{-8} \, \text{cm})^3 \] ### Step 3: Calculate the Volume Calculating the volume: \[ V = (3.147 \times 10^{-8})^3 = 3.116 \times 10^{-24} \, \text{cm}^3 \] ### Step 4: Determine the Number of Atoms per Unit Cell (Z) For a body-centered cubic (BCC) structure, the number of atoms per unit cell (Z) is 2. ### Step 5: Use the Density Formula The density (ρ) of the metal can be expressed using the formula: \[ \rho = \frac{Z \times \text{Atomic Weight}}{V \times N_A} \] Where: - \( N_A \) = Avogadro's number = \( 6.022 \times 10^{23} \, \text{mol}^{-1} \) Rearranging the formula to solve for Atomic Weight (A): \[ A = \frac{\rho \times V \times N_A}{Z} \] ### Step 6: Substitute the Known Values Substituting the known values into the equation: \[ A = \frac{10.2 \, \text{g/cm}^3 \times 3.116 \times 10^{-24} \, \text{cm}^3 \times 6.022 \times 10^{23} \, \text{mol}^{-1}}{2} \] ### Step 7: Calculate the Atomic Weight Calculating the numerator: \[ 10.2 \times 3.116 \times 10^{-24} \times 6.022 \times 10^{23} = 10.2 \times 3.116 \times 6.022 \times 10^{-1} \] \[ = 10.2 \times 18.74 \approx 191.1 \] Now divide by 2: \[ A = \frac{191.1}{2} \approx 95.55 \, \text{g/mol} \] ### Final Result The atomic weight of the unknown metal is approximately **95.55 g/mol**. ---
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