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Match Column - I with Column - II. {...

Match Column - I with Column - II.
`{:(,"Column - I",,"Column - II"),((A),"NaCl"("C.N. of "Na^(+)),(p),4),((B),"ZnS"("C.N. of "Zn^(+2)),(q),3),((C ),CaF_(2)("C.N. of "Ca^(2+)),(r ),6),((D),"CsCl"("C.N. of "Cs^(+)),(s),8),(,,(t),"anion in alternate tetrahedral void."):}`

Text Solution

AI Generated Solution

To solve the problem of matching Column - I with Column - II, we need to analyze the coordination numbers of the cations in the given compounds. Let's break it down step by step. ### Step 1: Analyze NaCl - **NaCl**: In NaCl, the anions (Cl^-) form a face-centered cubic (FCC) structure. The cations (Na^+) occupy half of the tetrahedral voids. - **Coordination Number**: For Na^+, the coordination number is **6**. ### Step 2: Analyze ZnS - **ZnS**: In ZnS, the anions (S^2-) also form a face-centered cubic (FCC) structure. The cations (Zn^2+) occupy alternate tetrahedral voids. ...
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