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Statement -1: DeltaH of a reaction is in...

Statement -1: `DeltaH` of a reaction is independent of temperature.
and Statement -2: `DeltaH^(@)` of a reacction `=sum H^(@) ("products") - sum H^(@)("reactants")`

A

Statement -1 is true, Statement -2 is true, Statement -2 is correct explanation for statement -4

B

Statement -1 is true, Statement-2 is True, Statement-2 is not a correct explanation for Statement -4

C

Statement-1 is true, Statement -2 is False.

D

Statement -1 is False, Statement -2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to evaluate the two statements provided: **Statement 1**: ΔH of a reaction is independent of temperature. **Statement 2**: ΔH° of a reaction = ΣH° (products) - ΣH° (reactants). ### Step-by-Step Solution: 1. **Evaluate Statement 1**: - The change in enthalpy (ΔH) of a reaction is not independent of temperature. - Enthalpy is defined as the total heat content of a system, and it can change with temperature. - The relationship can be expressed as ΔH = Cp * ΔT, where Cp is the molar heat capacity at constant pressure and ΔT is the change in temperature. - Therefore, as temperature changes, ΔH will also change. - **Conclusion**: Statement 1 is **incorrect**. 2. **Evaluate Statement 2**: - The change in standard enthalpy (ΔH°) for a reaction is calculated using the formula: ΔH° = ΣH° (products) - ΣH° (reactants). - This formula is derived from the definition of enthalpy change, which is the difference between the enthalpy of products and the enthalpy of reactants. - This is a fundamental principle in thermochemistry. - **Conclusion**: Statement 2 is **correct**. 3. **Final Conclusion**: - Since Statement 1 is incorrect and Statement 2 is correct, the overall conclusion is that Statement 1 is false and Statement 2 is true. - Therefore, the correct answer is option **D**: Statement 1 is false, Statement 2 is true.
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