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The conductivity of 0.02 N solution of a...

The conductivity of 0.02 N solution of a cell of KCl at `25^@C" is "2.765 xx 10^(-3) Scm^(-1)`. If the resistance of a cell containing this solution is 4000 ohm, what will be the cell constant?

A

`11.06 cm^(-1)`

B

`1.21 cm^(-1)`

C

`1.19 cm^(-1)`

D

`1.286cm^(-1)`

Text Solution

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The correct Answer is:
To find the cell constant (L/A) for the given KCl solution, we can use the relationship between conductivity (κ), resistance (R), and the cell constant (L/A). The formula we will use is: \[ \kappa = \frac{L}{A} \cdot \frac{1}{R} \] Where: - κ is the conductivity, - L is the length of the electrodes, - A is the cross-sectional area of the electrodes, - R is the resistance of the solution. ### Step-by-Step Solution: 1. **Identify the given values:** - Conductivity (κ) = \(2.765 \times 10^{-3} \, \text{S/cm}\) - Resistance (R) = \(4000 \, \Omega\) 2. **Rearrange the formula to solve for the cell constant (L/A):** \[ \frac{L}{A} = \kappa \cdot R \] 3. **Substitute the known values into the rearranged formula:** \[ \frac{L}{A} = (2.765 \times 10^{-3} \, \text{S/cm}) \cdot (4000 \, \Omega) \] 4. **Calculate the cell constant:** \[ \frac{L}{A} = 2.765 \times 10^{-3} \times 4000 \] \[ \frac{L}{A} = 11.06 \, \text{cm}^{-1} \] 5. **Final answer:** The cell constant (L/A) is \(11.06 \, \text{cm}^{-1}\).

To find the cell constant (L/A) for the given KCl solution, we can use the relationship between conductivity (κ), resistance (R), and the cell constant (L/A). The formula we will use is: \[ \kappa = \frac{L}{A} \cdot \frac{1}{R} \] Where: - κ is the conductivity, ...
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