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On the electrolysis of very dilute aqueo...

On the electrolysis of very dilute aqueous solution of `NaOH` using Pt electrodes

A

`H_2` is evolved at cathode

B

Na is evolved at cathade

C

`Q_2` is evołved at anode

D

`H_(2)` is evolved at anode

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of electrolysis of a very dilute aqueous solution of NaOH using platinum electrodes, we can follow these steps: ### Step 1: Understand the Electrolysis Process Electrolysis involves the decomposition of a compound in solution by passing an electric current through it. In this case, we are dealing with a dilute aqueous solution of sodium hydroxide (NaOH). ### Step 2: Identify the Electrodes In this scenario, we are using platinum electrodes. Platinum is an inert electrode, meaning it does not participate in the chemical reactions but serves as a conductor for the electric current. ### Step 3: Determine the Reactions at the Electrodes During electrolysis, oxidation occurs at the anode and reduction occurs at the cathode. - **At the Anode:** The hydroxide ions (OH⁻) are oxidized. The reaction can be represented as: \[ 4OH^{-} \rightarrow 2H_2O + O_2 + 4e^{-} \] This means that oxygen gas (O₂) is evolved at the anode. - **At the Cathode:** The hydrogen ions (H⁺) present in the solution are reduced. The reaction can be represented as: \[ 4H^{+} + 4e^{-} \rightarrow 2H_2 \] This means that hydrogen gas (H₂) is evolved at the cathode. ### Step 4: Identify the Gases Produced From the reactions, we can conclude: - At the cathode, hydrogen gas (H₂) is produced. - At the anode, oxygen gas (O₂) is produced. ### Step 5: Conclusion Based on the reactions occurring during the electrolysis of very dilute NaOH solution, we can summarize: - Hydrogen gas is evolved at the cathode. - Oxygen gas is evolved at the anode. ### Final Answer Thus, the correct option is: - **At cathode: H₂ is evolved; At anode: O₂ is evolved.**
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