Home
Class 12
CHEMISTRY
The potential associated. with each elec...

The potential associated. with each electrode is known as electrode potential. If the concentration of each species taking part in the electrode reaction is unity (if any gås appears in the electrode reaction, it is confined to 1 atmospheric pressure) and further the reaction is carried out at 298 K, then the potential of each electrode is said to be the standard electrode potential. By convention, the standard electrode potential of hydrogen electrode is 0:0 volt. The electrode potential value for each electrode process is a measure, of relative tendency of the active species in the process to remain in the oxidized / reduced form. A negative `E^@` means that the redox couple is a stronger reducing agent than the `H^(+)//H_2` couple. A positive E mears that the redox couple is a weaker reducing agent than. the `H^(+)//H` couple. The metal with greater positive value of standard reduction potentlal forms the oxide of greater thermal stability:
Which of the following metals will not displace hydrogen from water?

A

Mg

B

Zn

C

Sn

D

Ag

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given metals will not displace hydrogen from water, we need to analyze the standard reduction potentials of each metal and compare them to the standard reduction potential of the hydrogen electrode, which is defined as 0.0 volts. ### Step-by-Step Solution: 1. **Identify the Standard Reduction Potentials**: - For each metal, we need to find the standard reduction potential (E°) values. - **Magnesium (Mg)**: E° (Mg²⁺/Mg) = -2.37 V - **Zinc (Zn)**: E° (Zn²⁺/Zn) = -0.76 V - **Tin (Sn)**: E° (Sn²⁺/Sn) = -0.14 V - **Silver (Ag)**: E° (Ag⁺/Ag) = +0.80 V 2. **Understanding Displacement of Hydrogen**: - The reaction we are considering is: \[ M + 2H_2O \rightarrow M^{n+} + H_2 + 2OH^- \] - For a metal (M) to displace hydrogen from water, the oxidation potential of the metal must be greater than that of hydrogen. This means that the standard reduction potential of the metal must be less than 0 V (since E° for H⁺/H₂ is 0 V). 3. **Comparing E° Values**: - We compare the E° values of the metals with the hydrogen electrode: - **Mg**: -2.37 V (less than 0, can displace hydrogen) - **Zn**: -0.76 V (less than 0, can displace hydrogen) - **Sn**: -0.14 V (less than 0, can displace hydrogen) - **Ag**: +0.80 V (greater than 0, cannot displace hydrogen) 4. **Conclusion**: - Since only silver (Ag) has a positive standard reduction potential, it will not displace hydrogen from water. Therefore, the answer is: - **Silver (Ag)** will not displace hydrogen from water. ### Final Answer: **Ag (Silver)** will not displace hydrogen from water.
Promotional Banner

Similar Questions

Explore conceptually related problems

The potential associated. with each electrode is known as electrode potential. If the concentration of each species taking part in the electrode reaction is unity (if any gås appears in the electrode reaction, it is confined to 1 atmospheric pressure) and further the reaction is carried out at 298 K, then the potential of each electrode is said to be the standard electrode potential. By convention, the standard electrode potential of hydrogen electrode is 0:0 volt. The electrode potential value for each electrode process is a measure, of relative tendency of the active species in the process to remain in the oxidized / reduced form. A negative E^@ means that the redox couple is a stronger reducing agent than the H^(+)//H_2 couple. A positive E mears that the redox couple is a weaker reducing agent than. the H^(+)//H couple. The metal with greater positive value of standard reduction potentlal forms the oxide of greater thermal stability: Which of the following oxides will be themally most stable?

The potential associated with each electrode is known as electrode potential. If the concentration of each species taking part in the electrode reaction is unity (if any appears in the electrode reaction, it is confined to 1 atmospheric pressure) and further the reaction is carried out at 298 K, then the potential of each electrode is said to the standard electrode potential. By convention, the standard electrode potential of hydrogen electrode is 0.0 volt. The electrode potential value for each electrode process is a measure of relative tendency of the active species in the process to remain in the oxidised/reduced form. A negative E^(@) means that the redox couple is a stronger reducing agent than the H^(+)//H_(2) couple. A positive E^(@) means that the redox couple is a weaker reducing agent than the H^(+)//H_(2) couple. The metal with greater positive value of standard reduction potential forms the oxide of greater thermal stability. Which of the following reactions is not correct ?

The potential associated with each electrode is known as electrode potential. If the concentration of each species taking part in the electrode reaction is unity (if any appears in the electrode reaction, it is confined to 1 atmospheric pressure) and further the reaction is carried out at 298 K, then the potential of each electrode is said to the standard electrode potential. By convention, the standard electrode potential of hydrogen electrode is 0.0 volt. The electrode potential value for each electrode process is a measure of relative tendency of the active species in the process to remain in the oxidised/reduced form. A negative E^(@) means that the redox couple is a stronger reducing agent than the H^(+)//H_(2) couple. A positive E^(@) means that the redox couple is a weaker reducing agent than the H^(+)//H_(2) couple. The metal with greater positive value of standard reduction potential forms the oxide of greater thermal stability. Which of the following couples will have highest value of emf ?

The potential associated. with each electrode is known as electrode potential. If the concentration of each species taking part in the electrode reaction is unity (if any gås appears in the electrode reaction, it is confined to 1 atmospheric pressure) and further the reaction is carried out at 298 K, then the potential of each electrode is said to be the standard electrode potential. By convention, the standard electrode potential of hydrogen electrode is 0:0 volt. The electrode potential value for each electrode process is a measure, of relative tendency of the active species in the process to remain in the oxidized / reduced form. A negative E^@ means that the redox couple is a stronger reducing agent than the H^(+)//H_2 couple. A positive E mears that the redox couple is a weaker reducing agent than. the H^(+)//H couple. The metal with greater positive value of standard reduction potentlal forms the oxide of greater thermal stability: Given the standard reduction potentials. E_(K^(+)//K)^(@)=-2.93V, E_(Ag^(+)//Ag)^(@)=+0.80V, E_(Hg^(+)//Hg)^(@)=0.79V E_(Mg^(+)//Mg)^(@)=-2.37V, E_(Cr^(3+)//Cr)^(@)=-0.74V The correct increasing order of reducing power is:

Define standard electrode potential.

What is electrode potential?

What is electrode potential?

The electrode potential of hydrogen electrode at the pH=12 will be

Electrode potential depends upon

The potential of hydrogen electrode having a pH=10 is