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If a centi normal solution of NH4OH has ...

If a centi normal solution of `NH_4OH` has molar conductivity equal to `9.6 Omega^(-1) cm^(2) mol^(-1)`. what will be the per cent dissociation of `NH_4OH` at this dilution.

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To solve the problem, we need to find the percent dissociation of ammonium hydroxide (NH₄OH) in a centi-normal solution given its molar conductivity. Here are the steps to arrive at the solution: ### Step-by-Step Solution: 1. **Understand the Given Data:** - Molar conductivity (Λ) of the centi-normal solution of NH₄OH = 9.6 Ω⁻¹ cm² mol⁻¹ - Molar conductivity at infinite dilution (Λ°) of NH₄OH = 240 Ω⁻¹ cm² mol⁻¹ (This value is generally known or can be looked up in tables.) 2. **Use the Formula for Percent Dissociation:** - The formula for calculating the degree of dissociation (α) is given by: \[ \alpha = \frac{\text{Molar Conductivity at given concentration (Λ)}}{\text{Molar Conductivity at infinite dilution (Λ°)}} \] 3. **Substitute the Values into the Formula:** - Substitute the given values into the formula: \[ \alpha = \frac{9.6 \, \Omega^{-1} \, \text{cm}^2 \, \text{mol}^{-1}}{240 \, \Omega^{-1} \, \text{cm}^2 \, \text{mol}^{-1}} \] 4. **Calculate α:** - Perform the division: \[ \alpha = \frac{9.6}{240} = 0.04 \] 5. **Convert α to Percent Dissociation:** - To find the percent dissociation, multiply α by 100: \[ \text{Percent Dissociation} = \alpha \times 100 = 0.04 \times 100 = 4\% \] ### Final Answer: The percent dissociation of NH₄OH at this dilution is **4%**.
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