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Magnesium obtained by the electrolysis o...

Magnesium obtained by the electrolysis of fused `MgCl_(2)` using

A

a nickel cathode and graphite anode

B

a nickel container as cathode and an iron anode

C

an iron container as cathode and graphite anode

D

a lead cathode and a platinum anode

Text Solution

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The correct Answer is:
To solve the question regarding the electrolysis of fused MgCl₂ and the materials used for the cathode and anode, we can break down the process step by step. ### Step-by-Step Solution: 1. **Understand the Electrolysis Process**: - Electrolysis involves the breakdown of a compound into its elements using electricity. In the case of fused MgCl₂, we are interested in the production of magnesium (Mg) and chlorine (Cl₂). 2. **Identify the Electrolyte**: - The electrolyte here is fused magnesium chloride (MgCl₂). When melted, MgCl₂ dissociates into magnesium ions (Mg²⁺) and chloride ions (Cl⁻). 3. **Determine the Reactions at the Electrodes**: - At the cathode (negative electrode), reduction occurs. The magnesium ions (Mg²⁺) gain electrons to form magnesium metal: \[ \text{Mg}^{2+} + 2e^- \rightarrow \text{Mg} \] - At the anode (positive electrode), oxidation occurs. The chloride ions (Cl⁻) lose electrons to form chlorine gas: \[ 2\text{Cl}^- \rightarrow \text{Cl}_2 + 2e^- \] 4. **Select Appropriate Materials for Electrodes**: - The materials used for the electrodes must be able to withstand the conditions of electrolysis and not react with the products formed. - Common choices for electrodes in this process include: - Cathode: Iron container (which can act as a cathode). - Anode: Graphite (which is stable and can be used as an anode). 5. **Evaluate the Options Given**: - Option A: Nickel cathode and graphite anode - Option B: Nickel container as cathode and iron anode - Option C: Iron container as cathode and graphite anode - Option D: Lead cathode and platinum anode - Based on the analysis, the most suitable option is **Option C: Iron container as cathode and graphite anode**. ### Final Answer: Magnesium is obtained by the electrolysis of fused MgCl₂ using an **iron container as cathode and graphite anode** (Option C). ---
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