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Which of the following species can acts ...

Which of the following species can acts as bronsted base as well as a Lewis base?

A

`NO_(3)^(-)`,

B

`CN^(-)`

C

`NH_(3)`

D

`BF_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which species can act as both a Brønsted base and a Lewis base, we need to analyze each option given in the question. ### Step-by-Step Solution: 1. **Understand Brønsted and Lewis Bases**: - A **Brønsted base** is a species that can accept a proton (H⁺). - A **Lewis base** is a species that can donate an electron pair. 2. **Evaluate Each Species**: - **Option 1: NO3⁻ (Nitrate ion)**: - *Brønsted Base*: NO3⁻ can accept a proton (H⁺) to form HNO3 (nitric acid). Thus, it acts as a Brønsted base. - *Lewis Base*: NO3⁻ can donate an electron pair to form a bond with H⁺. Therefore, it also acts as a Lewis base. - Conclusion: NO3⁻ acts as both a Brønsted base and a Lewis base. - **Option 2: CN⁻ (Cyanide ion)**: - *Brønsted Base*: CN⁻ can accept a proton (H⁺) to form HCN (hydrogen cyanide). Thus, it acts as a Brønsted base. - *Lewis Base*: CN⁻ can donate an electron pair to H⁺, forming a bond. Therefore, it also acts as a Lewis base. - Conclusion: CN⁻ acts as both a Brønsted base and a Lewis base. - **Option 3: NH3 (Ammonia)**: - *Brønsted Base*: NH3 can accept a proton (H⁺) to form NH4⁺ (ammonium ion). Thus, it acts as a Brønsted base. - *Lewis Base*: NH3 has a lone pair of electrons on nitrogen, which it can donate to H⁺ to form a bond. Therefore, it also acts as a Lewis base. - Conclusion: NH3 acts as both a Brønsted base and a Lewis base. - **Option 4: BF3 (Boron trifluoride)**: - *Brønsted Base*: BF3 cannot accept a proton because it is electron deficient and does not have available electrons to bond with H⁺. Therefore, it does not act as a Brønsted base. - *Lewis Base*: BF3 can accept an electron pair due to its electron deficiency, which allows it to act as a Lewis acid, but not a Lewis base. - Conclusion: BF3 does not act as a Brønsted base or a Lewis base. 3. **Final Conclusion**: - The species that can act as both a Brønsted base and a Lewis base are: **NO3⁻, CN⁻, and NH3**. ### Answer: The correct options are 1 (NO3⁻), 2 (CN⁻), and 3 (NH3). ---
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