Home
Class 12
CHEMISTRY
Write down the IUPAC nomenclature of the...

Write down the IUPAC nomenclature of the following:(a)`NH_(4)[Cr(NCS)_(4)(NH_(3))_(2)]`(b)`K_(3)[Cr(C_(2)O_(4))_(3)]` `
(ii)(a) K_(2)[OsCl_(5)N]`(b) `[Zn(NCS)_(4)]^(2-)`
(c) `[Cd(SCN)_(4)]^(3-)`(d) `[Cr(en)_(3)]Cl_(3)`
(e) `K_(4)[Fe(NC)_(6)]`
`[Co (NH_(3))_(5) ONO]Cl_(2)`
(g) `K_(3)[Cr(CN)_(6)]`(h) `[Co(NH_(3))_(5)NO_(2)(NO)_(3))_(2)]`
(i)  `[Co(en)(NH_(3))_(2)ClBr]NO_(3)`
(j) `Na_(2) [Fe(CN)_(5)NO]`
(iii) Write the formula for each of the following complexes.
(a) Chlorodiammineplatinum (II) ion
(b) Dichlorobis (ethylenediamine) cobalt(II) ion
(c) Dichlorotetramminecobalt (iii) ion
(d) Potassium pentacyanonitrosylcobaltate (III)
(e) Sodium ethylenediaminetetraacetato chromate (ll) (f)
Carbonylchlorobis(triphenylphosphine)iridium(I)
(g) Ammoniumtrisoxalatocobaltate(iii)
Pentaaquahydroxochromium(lll)sulphate
(i) Hexaaquavanadium(II) chloride
(j)Tetraamminedichlorocobalt(II) hexacyanochromate(V)

Text Solution

AI Generated Solution

Let's break down the IUPAC nomenclature of the given coordination compounds step by step. ### Part (i): IUPAC Nomenclature #### (a) `NH₄[Cr(NCS)₄(NH₃)₂]` 1. Identify the cation and anion: The cation is `NH₄⁺` (ammonium) and the anion is `[Cr(NCS)₄(NH₃)₂]`. 2. Name the ligands: - `NCS` is thiocyanato, and since there are four of them, it becomes tetra-thiocyanato. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Write the IUPAC name of the following : (a) [Cr(acac)_(3)] (b) [V(H_(2)O)_(6)]Cl_(3) ( c) (NH_(4))_(3)[Co(C_(2)O_(4))_(3)] (d) K_(2)[CrO_(4)]

Write the IUPAC names of the following coordination compounds: (a) [Pt(NH_(3))_(2)Cl(NO_(2))] (b) K_(3)[Cr(C_(2)O_(4))_(3)] (c) [CoCl_(2)(en)_(2)]Cl (d) [Co(NH_(3))]Cl (e) Hg[Co(SCN)_(4)]

Write the IUPAC name for the following compounds (a) [Co(NH_(3))_(5)ONO]Cl_(2) (b) K_(3)[Cr(CN)_(6)] .

Write the IUPAC name of the following : (i) [Co(NH_(3))_(6)]Cl_(3) (ii) [NiCl_(4)]^(2-) (iii) K_(3)[Fe(CN)_(6)]

Which of the following will have three stereoisomeric forms? (i) [Cr(NO_(3))_(3)(NH_(3))_(3)] (ii) K_(3)[Co(C_(2)O_(4))_(3)] (iii) K_(3)[CoCl_(2)(C_(2)O_(4))_(2)] (iv) [CoBrCl(en)_(2)]

Write down the IUPAC name of K_(2)[Fe(NC)_(3)Cl_(2)(NH_(3))_2]

Which of the following will have two stereoisomeric forms? (I) [Cr(NO_(3))_(3)(NH_(3))_(3)] (II) K_(3)[Fe(C_(2)O_(4))_(3)] (III) [CoCl_(2)(en)_(2)]^(+) (IV) [CoBrCl(o x)_(2)]^(3-)

[Cr(NH_(3))_(5)NO_(2)]SO_(4) and [Cr(NH_(3))_(5)ONO]SO_(4) are related to each other as: .

Write the IUPAC names of the following coordinates compounds : (1) [Co(NH_(3))_(5)Cl]Cl_(2) (2) K_(2)[PdCl_(4)] (3) [Cr(H_(2)O)_(4)Cl_(2)]^(+) (4) K_(3)[Fe(CN)_(5)NO]

Name the type of isomerism exibited by the following isomers : (1) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)] (2) [Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O (3) [Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2) (4) [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)