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The ammonia evolved from 0.5g of the org...

The ammonia evolved from 0.5g of the organic compound in Kjeldahl's estimation of nitrogen neutralizes 10 ml of 1 M `H_2SO_4`. Identify the correct statement(s) out of the following:

A

Percentage of nitrogen in the organic compound is 56%

B

Milliequivalents of ammonia produced in the solution are 20

C

If the evolved ammonia were neutralized by 10 ml of 1 M HCl, the % of nitrogen would . have been 28%

D

It is a gravimetric estimation

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the percentage of nitrogen in the organic compound based on the information provided. Here’s a step-by-step breakdown of the solution: ### Step 1: Understand the Reaction The ammonia evolved from the organic compound neutralizes sulfuric acid (H₂SO₄). The amount of H₂SO₄ used is given as 10 mL of 1 M solution. ### Step 2: Calculate Moles of H₂SO₄ Using the molarity and volume of H₂SO₄, we can calculate the number of moles of H₂SO₄: \[ \text{Moles of H₂SO₄} = \text{Molarity} \times \text{Volume (L)} = 1 \, \text{mol/L} \times 0.010 \, \text{L} = 0.010 \, \text{mol} \] ### Step 3: Determine Moles of Ammonia (NH₃) The reaction between ammonia and sulfuric acid is: \[ 2 \, \text{NH₃} + \text{H₂SO₄} \rightarrow \text{(NH₄)₂SO₄} \] From the stoichiometry of the reaction, 1 mole of H₂SO₄ reacts with 2 moles of NH₃. Therefore, the moles of NH₃ produced can be calculated as: \[ \text{Moles of NH₃} = 2 \times \text{Moles of H₂SO₄} = 2 \times 0.010 \, \text{mol} = 0.020 \, \text{mol} \] ### Step 4: Calculate Mass of Nitrogen in Ammonia The molar mass of ammonia (NH₃) is approximately 17 g/mol, and since each mole of NH₃ contains 1 mole of nitrogen (N), we can find the mass of nitrogen: \[ \text{Mass of NH₃} = \text{Moles of NH₃} \times \text{Molar Mass of NH₃} = 0.020 \, \text{mol} \times 17 \, \text{g/mol} = 0.34 \, \text{g} \] Since nitrogen has a molar mass of approximately 14 g/mol, the mass of nitrogen in the ammonia is: \[ \text{Mass of Nitrogen} = \text{Moles of NH₃} \times 14 \, \text{g/mol} = 0.020 \, \text{mol} \times 14 \, \text{g/mol} = 0.28 \, \text{g} \] ### Step 5: Calculate Percentage of Nitrogen in the Organic Compound Now, we can find the percentage of nitrogen in the original organic compound: \[ \text{Percentage of Nitrogen} = \left( \frac{\text{Mass of Nitrogen}}{\text{Mass of Organic Compound}} \right) \times 100 = \left( \frac{0.28 \, \text{g}}{0.5 \, \text{g}} \right) \times 100 = 56\% \] ### Conclusion The percentage of nitrogen in the organic compound is 56%. Therefore, the correct statement is that the percentage of nitrogen in the organic compound is 56%. ---
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