Home
Class 12
CHEMISTRY
Chlorobenzene when treated with ethanoli...

Chlorobenzene when treated with ethanolic `AgNO_(3)` it does not give white precipitate. Explain.

Text Solution

Verified by Experts

Aromatic compounds in which halogen is attached directly to the aromatic nucleus (e.g. chlorobenzene) do not react with ethanolic `AgNO_(3)` even on heating probably due to high bond energy of C-Cl bond which has partial double bond character.
Promotional Banner

Similar Questions

Explore conceptually related problems

Alcoholic "AgNO"_(3) does not give precipitate with:

AgNO_(3) solution will not give white precipitate with

Cu^(2+) ions give white precipitate with :

"AgNO"_(3) does not give precipitate with chloroform because:

A six coordination complex of formula CrCl_(3)*6H_(2)O has green colour. A 0.1 M solution of the complex when treated with excess of AgNO_(3) gave 28.7g of white precipitate. The formula of the complex would be:

A six coordination complex of formula CrCl_(3)*6H_(2)O has green colour. A 0.1 M solution of the complex when treated with excess of AgNO_(3) gas 28.7g of white precipitate. The formula of the complex would be:

AgNO_(3) gives red precipitate with

A white crystalline compound (X) swells open heating and gives violet-coloured flame. Its aqueous solution gives the following reactions : (a) A white precipitate is formed, with BaCl_(2) in presence of HCl . (b) When treated with excess of NH_(4) OH , it gives white gelatinous precipitate. the white precipitate dissolves in NaOH and reappears on boiling with concentrated solution of NH_(4) Cl . ( c) It gives yellow precipitate with cobaltinitrite solution. Identify (X) and explain the reaction at steps a, b and c .

A compound (C_(5)H_(8)) reacts with ammoniacal AgNO_(3) to give a white precipitate and reacts with excess of KMnO_(4) solution to give (CH_(3))_(2)CH-COOH . The compound is

A white precipitate is obtained when: