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{:(,"Column-I(Reaction)",,"Column-II(Pro...

`{:(,"Column-I(Reaction)",,"Column-II(Product)"),((A),"Chloroform reacts with "HNO_(3)" acid to form an insecticide",(p),"gammaxene"),((B),"Silver acetate gets converted into methyl bromide on reaction with "Br_(2)" in "C Cl_(4),(r),"Diphenyl trichloro ethane"),((C),"Chlorobenzene in the presence of conc." H_(2)SO_(4)" reacts with trichloro acetaldehyde",(r),"Chloropicrin"),((D),"Benzene react with "Cl_(2)" in presence of sunlight.",(s),"Compound containing Oxygen"),(,,(t),"Borodine Hunsdiecker reaction"):}`

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To solve the matching question between the reactions in Column-I and the products in Column-II, we will analyze each reaction step by step. ### Step-by-Step Solution: 1. **Reaction A: Chloroform reacts with HNO3 to form an insecticide.** - Chloroform (CCl3H) reacts with nitric acid (HNO3). - The reaction leads to the formation of chloropicrin (CCl3NO2) by the removal of water. - **Match:** A → R (Chloropicrin) 2. **Reaction B: Silver acetate gets converted into methyl bromide on reaction with Br2 in CCl4.** - Silver acetate (C2H3O2Ag) reacts with bromine (Br2) in carbon tetrachloride (CCl4). - The reaction involves a radical mechanism where the acetate group is replaced by a bromine atom, forming methyl bromide (CH3Br). - This reaction is known as the Borodin-Hunsdecker reaction. - **Match:** B → T (Borodin-Hunsdecker reaction) 3. **Reaction C: Chlorobenzene in the presence of conc. H2SO4 reacts with trichloroacetaldehyde.** - Chlorobenzene reacts with trichloroacetaldehyde (CCl3CHO) in the presence of concentrated sulfuric acid (H2SO4). - The reaction involves the formation of chloropicrin (CCl3NO2) through dehydration. - **Match:** C → S (Compound containing Oxygen) 4. **Reaction D: Benzene reacts with Cl2 in the presence of sunlight.** - Benzene (C6H6) reacts with chlorine (Cl2) in the presence of sunlight. - This reaction leads to the formation of hexachlorocyclohexane (gamma-xene). - **Match:** D → P (Gamma-xene) ### Final Matches: - A → R (Chloropicrin) - B → T (Borodin-Hunsdecker reaction) - C → S (Compound containing Oxygen) - D → P (Gamma-xene)
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