Home
Class 12
CHEMISTRY
What is the number of optically active i...

What is the number of optically active isomers of compound having molecular formula `C_(5)H_(9)Cl`.

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of optically active isomers for the compound with the molecular formula C₅H₉Cl, we need to analyze the possible structures and identify chiral centers. Here’s a step-by-step solution: ### Step 1: Identify the Structure The molecular formula C₅H₉Cl suggests that the compound is likely an alkene due to the degree of unsaturation (since a saturated alkane with 5 carbons would have the formula C₅H₁₂). The presence of chlorine also indicates that it could be a haloalkene. ### Step 2: Draw Possible Structures 1. **Position of the Double Bond**: The double bond can be located in different positions. For five carbons, the double bond can be: - Between C1 and C2 - Between C2 and C3 - Between C3 and C4 - Between C4 and C5 2. **Chlorine Placement**: For each double bond position, chlorine can be placed on different carbon atoms. ### Step 3: Identify Chiral Centers A chiral center is a carbon atom that has four different substituents. We need to analyze each structure to find chiral centers: - For structures where the double bond is between C1 and C2, and C2 has a chlorine and two different groups, it can be chiral. - Similarly, for other positions of the double bond, we check if any carbon has four different substituents. ### Step 4: Count Optically Active Isomers 1. **Isomers with Double Bond at C1-C2**: - Structure 1: Chiral (two configurations possible) - Structure 2: Chiral (two configurations possible) 2. **Isomers with Double Bond at C2-C3**: - Structure 3: Chiral (two configurations possible) - Structure 4: Not chiral (due to symmetry) 3. **Isomers with Double Bond at C3-C4**: - Structure 5: Not chiral (due to symmetry) - Structure 6: Chiral (two configurations possible) 4. **Isomers with Double Bond at C4-C5**: - Structure 7: Not chiral (due to symmetry) ### Step 5: Total Count After analyzing all possible structures, we find: - From double bond at C1-C2: 2 optically active isomers - From double bond at C2-C3: 2 optically active isomers - From double bond at C3-C4: 1 optically active isomer - From double bond at C4-C5: 0 optically active isomers Adding these gives us a total of **4 optically active isomers**. ### Final Answer The number of optically active isomers of the compound with the molecular formula C₅H₉Cl is **4**. ---

To determine the number of optically active isomers for the compound with the molecular formula C₅H₉Cl, we need to analyze the possible structures and identify chiral centers. Here’s a step-by-step solution: ### Step 1: Identify the Structure The molecular formula C₅H₉Cl suggests that the compound is likely an alkene due to the degree of unsaturation (since a saturated alkane with 5 carbons would have the formula C₅H₁₂). The presence of chlorine also indicates that it could be a haloalkene. ### Step 2: Draw Possible Structures 1. **Position of the Double Bond**: The double bond can be located in different positions. For five carbons, the double bond can be: - Between C1 and C2 ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Compound having molecular formula C_(5)H_(12)O cannot show

The total number of geometrical isomers of most compound having molecular formula C_4H_8 is

Write the isomers of the compound having formula C_(4)H_(9)Br .

No. of acyclic isomers of the compound having the molecular formula C_(4)H_(10)O is :

Draw the isomers of a compound with the molecular formula C_(4)H_(4)O_(4)

The compound having the molecular formula C_(3)H_(9)N can represent

Write all the acyclic and cyclic isomers of a compound having molecular formula C_(3)H_(6)O .

Number of acyclic structural isomers of the compound having the molecular formula C_4H_10O is

An optically inactive compound (A) having molecular formula C_(4)H_(11)H on treatment with HNO_(2) gave an alconot (B) which on heating with conc. H_(2)SO_(4) at 440 k gave an alkene ( C) . ( C) on treatment with HBr gave an optically active compound (D ) having molecular formula C_(4)H_(9)Br Identify (A) ,(B) ,(C) and (D).