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Magnesium on heating reacts vigorously w...

Magnesium on heating reacts vigorously with element X to produce compound Y. An aqueous solution of Y, when treated with aqueous silver nitrate , gives a white precipitate that is readily soluble in dilute aqueous ammonia. What is the minium mass of X that is needed to react completely with 4.05g of magnesium

A

11.83g

B

5.92g

C

5.33g

D

2.67g

Text Solution

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The correct Answer is:
To solve the problem step by step, we will follow the reasoning provided in the video transcript and perform the necessary calculations. ### Step 1: Identify the Reaction Magnesium (Mg) reacts with element X to produce compound Y. Given that the aqueous solution of Y reacts with silver nitrate (AgNO3) to form a white precipitate that is soluble in dilute ammonia, we can deduce that Y contains chlorine (Cl). The white precipitate formed is silver chloride (AgCl). ### Step 2: Determine Element X Since Y must contain chlorine, we can conclude that element X is chlorine (Cl). Therefore, the reaction can be written as: \[ \text{Mg} + \text{Cl}_2 \rightarrow \text{MgCl}_2 \] ### Step 3: Calculate Moles of Magnesium We are given the mass of magnesium: - Mass of magnesium (Mg) = 4.05 g To find the number of moles of magnesium, we use the formula: \[ \text{Number of moles} = \frac{\text{Mass}}{\text{Molar mass}} \] The molar mass of magnesium (Mg) is approximately 24.31 g/mol. Thus: \[ \text{Number of moles of Mg} = \frac{4.05 \, \text{g}}{24.31 \, \text{g/mol}} \approx 0.1663 \, \text{moles} \] ### Step 4: Determine Moles of Chlorine Required From the balanced reaction, we see that 1 mole of magnesium reacts with 1 mole of chlorine gas (Cl2). Therefore, the number of moles of Cl2 required is equal to the number of moles of Mg: \[ \text{Moles of Cl}_2 = 0.1663 \, \text{moles} \] ### Step 5: Calculate Mass of Chlorine Now, we need to calculate the mass of chlorine gas (Cl2) required. The molar mass of Cl2 is approximately 70.90 g/mol. We can use the formula: \[ \text{Mass} = \text{Number of moles} \times \text{Molar mass} \] Thus: \[ \text{Mass of Cl}_2 = 0.1663 \, \text{moles} \times 70.90 \, \text{g/mol} \approx 11.82 \, \text{g} \] ### Step 6: Round to Appropriate Significant Figures Rounding the mass of chlorine to three significant figures gives us: \[ \text{Mass of Cl}_2 \approx 11.83 \, \text{g} \] ### Conclusion The minimum mass of element X (chlorine) needed to react completely with 4.05 g of magnesium is approximately **11.83 g**.
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