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The reaction of chloroform with acetone ...

The reaction of chloroform with acetone gives

A

chloral

B

chloretone

C

mesitylene

D

ethylidene chloride

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of chloroform with acetone, we will follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are chloroform (CHCl3) and acetone (CH3COCH3). ### Step 2: Determine the Reaction Conditions The reaction typically occurs in a basic medium. This is crucial because the presence of a base facilitates the reaction. ### Step 3: Understand the Mechanism In a basic medium, chloroform can undergo a reaction known as the haloform reaction. The base deprotonates acetone, forming an enolate ion, which then attacks the carbon atom of chloroform. ### Step 4: Write the Reaction The reaction can be represented as follows: 1. The enolate ion from acetone attacks chloroform: \[ \text{CHCl}_3 + \text{CH}_3\text{COCH}_3 \rightarrow \text{CCl}_3\text{C(OH)(CH}_3)_2 \] 2. The product formed is trichloro-2-methylpropan-2-ol, commonly known as chloritone. ### Step 5: Identify the Product The final product of the reaction is chloritone (CCl3C(OH)(CH3)2). ### Conclusion The reaction of chloroform with acetone gives chloritone.
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