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Which of the following statements regard...

Which of the following statements regarding the molecule `CH_(2)=C=CH_(2)` is NOT correct?

A

Both the `pi` bonds are present in the same plane

B

The central carbon atom is sp hybridized while the terminal atoms are `sp^(2)` hybridized

C

the molecular is linear

D

the molecule contains six `sigma` bonds and two `pi` bonds.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement regarding the molecule \( CH_2=C=CH_2 \) is NOT correct, we will analyze each statement one by one. ### Step 1: Analyze the structure of the molecule The molecule \( CH_2=C=CH_2 \) consists of three carbon atoms connected by double bonds. The structure can be represented as: ``` H H \ / C // \ C C \ / H H ``` ### Step 2: Determine the hybridization of the carbon atoms 1. **Terminal Carbons (C1 and C3)**: Each terminal carbon (C1 and C3) is bonded to two hydrogen atoms and one carbon atom through a double bond. Therefore, they are **sp² hybridized**. 2. **Central Carbon (C2)**: The central carbon is bonded to two other carbon atoms through double bonds. Thus, it is **sp hybridized**. ### Step 3: Count the sigma and pi bonds - **Sigma Bonds**: - Each C-H bond is a sigma bond (2 C-H bonds). - Each C=C double bond consists of one sigma bond. - Therefore, the total number of sigma bonds is: - 2 (C1-H) + 2 (C3-H) + 1 (C1=C2) + 1 (C2=C3) = 6 sigma bonds. - **Pi Bonds**: - Each C=C double bond has one pi bond. - Therefore, the total number of pi bonds is: - 1 (C1=C2) + 1 (C2=C3) = 2 pi bonds. ### Step 4: Analyze the statements 1. **Statement 1**: "Both the pi bonds are present in the same plane." - **Analysis**: The pi bonds are formed from the unhybridized p orbitals. Since the p orbitals are oriented perpendicular to each other, this statement is **NOT correct**. 2. **Statement 2**: "The central carbon atom is sp hybridized while the terminal atoms are sp² hybridized." - **Analysis**: This statement is **correct**. 3. **Statement 3**: "The molecule is linear." - **Analysis**: The molecule has a linear arrangement due to the sp hybridization of the central carbon, making this statement **correct**. 4. **Statement 4**: "The molecule contains 6 sigma bonds and 2 pi bonds." - **Analysis**: As calculated, this statement is **correct**. ### Conclusion The statement that is NOT correct is: **"Both the pi bonds are present in the same plane."**
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