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The reagent required to convert propene ...

The reagent required to convert propene to 1-propanol is

A

`B_(2)H_(6)` followed by `H_(2)O_(2)//NaOH`

B

conc. `H_(2)SO_(4)` followed by hydrolysis with boiling water

C

HBr followed by hydrolysis with aqueous KOH

D

`Hg(OCOCH_(3))_(2)` followed by reduction with `NaBH_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To convert propene (CH3-CH=CH2) to 1-propanol (CH3-CH2-CH2OH), we can use the hydroboration-oxidation reaction. Here’s a step-by-step solution: ### Step 1: Identify the starting material and the desired product - **Starting material**: Propene (CH3-CH=CH2) - **Desired product**: 1-Propanol (CH3-CH2-CH2OH) ### Step 2: Choose the appropriate reagent The reagent required for the conversion of propene to 1-propanol is **B2H6** (diborane) followed by **H2O2** (hydrogen peroxide) in the presence of **NaOH** (sodium hydroxide). ### Step 3: Hydroboration of Propene 1. **Reaction with B2H6**: - Propene reacts with diborane (B2H6). - The boron atom from B2H6 adds to the less substituted carbon of the double bond (the terminal carbon), while a hydrogen atom adds to the more substituted carbon. - This results in the formation of trialkylborane. ### Step 4: Oxidation of Trialkylborane 2. **Oxidation with H2O2 and NaOH**: - The trialkylborane formed in the previous step is then treated with hydrogen peroxide (H2O2) in the presence of sodium hydroxide (NaOH). - This reaction leads to the replacement of the boron atom with a hydroxyl group (-OH), yielding 1-propanol. ### Step 5: Final product - The final product after the hydroboration-oxidation reaction is 1-propanol (CH3-CH2-CH2OH). ### Conclusion The reagent required to convert propene to 1-propanol is **B2H6 followed by H2O2 in NaOH**. ---
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