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Test (Q). A compound 'X' was fused with ...

Test (Q). A compound 'X' was fused with Na metal and the extract gave a white precipitate with `AgNO_(3)`. The Lassaigne's extract gave red colouration with neutral `FeCl_(3)`. Test R while compound 'Y' when fused with Na metal and subsequent analysis on its Lassaigne's extract did not give any characteristic test. Test S while compound Y on fusion with fusion mixture (sodium carbonate+potassium nitrate) or `Na_(2)O_(2)`, followed by extraction, followed by addition of conc. `HNO_(3)` and ammonium molybdate gave a yellow precipitate
Q. Compound X

A

will contain halogens

B

may contain halogens

C

may contain only sulphur

D

will contain nitrogen

Text Solution

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The correct Answer is:
### Step-by-Step Solution: 1. **Understanding the Problem**: We have a compound 'X' that was fused with sodium metal, and the resulting extract gave a white precipitate with AgNO3 and a red coloration with neutral FeCl3. We need to determine the composition of compound 'X'. 2. **Analyzing the White Precipitate with AgNO3**: - The formation of a white precipitate when the extract is treated with AgNO3 indicates the presence of halogens, specifically chlorine (Cl). - The reaction can be represented as: \[ \text{NaCl} + \text{AgNO}_3 \rightarrow \text{AgCl (white precipitate)} + \text{NaNO}_3 \] - This confirms that compound 'X' contains chlorine. 3. **Analyzing the Red Coloration with Neutral FeCl3**: - The red coloration with neutral FeCl3 indicates the presence of thiocyanate ions (SCN^-), which suggests that sulfur (S) and nitrogen (N) are also present in compound 'X'. - The reaction can be represented as: \[ \text{NaSCN} + \text{FeCl}_3 \rightarrow \text{Fe(SCN)}^{3+} + \text{NaCl} \] - The Fe(SCN)^{3+} complex gives a red coloration, confirming the presence of both sulfur and nitrogen in compound 'X'. 4. **Conclusion about Compound 'X'**: - From the tests, we conclude that compound 'X' contains chlorine (a halogen), sulfur, and nitrogen. 5. **Evaluating the Options**: - **Will contain halogens**: This is correct, as we confirmed the presence of chlorine. - **May contain halogens**: This is incorrect, as we have definitive evidence of halogen presence. - **May contain only sulfur**: This is incorrect, as we have confirmed the presence of chlorine and nitrogen as well. - **Will contain nitrogen**: This is correct, as we confirmed the presence of nitrogen. ### Final Answer: - Compound 'X' will contain halogens and nitrogen.
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