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Potassium carbonate cannot be prepared b...

Potassium carbonate cannot be prepared by Solvay process. Why ?

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Potassium carbonate cannot be prepared by Solvay process because potassium bicarbonate being more soluble than sodium bicarbonate does not get precipitated when CO, is passed through a concentrated solution of KCl saturated with ammonia.
KCI+ `CO_(2) + NH_(3) + H_(2)O rarr KHCO_(3) + NH_(4)CI`
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