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A monatomic gas undergoes a thermodynami...

A monatomic gas undergoes a thermodynamic process such that `Tprop V^(-2/7)` (T = temperature and V = volume of the gas) As heat is supplied to the gas, choose INCORRECT option.

A

ms velocity of gas molecules increases

B

rms velocity of gas molecules decreases

C

work done on the gas is positive

D

density of the gas increases

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The correct Answer is:
To solve the problem, we need to analyze the thermodynamic process of a monatomic gas under the given condition that temperature \( T \) is proportional to \( V^{-2/7} \). We will derive relationships and determine the incorrect option based on the implications of supplying heat to the gas. ### Step-by-Step Solution: 1. **Understanding the Relationship**: Given that \( T \propto V^{-2/7} \), we can express this as: \[ T = k \cdot V^{-2/7} \] where \( k \) is a constant. 2. **Rearranging the Equation**: To eliminate \( T \), we can multiply both sides by \( V^{2/7} \): \[ T \cdot V^{2/7} = k \] This indicates that \( T \cdot V^{2/7} \) remains constant. 3. **Using the Ideal Gas Law**: From the ideal gas law, we know: \[ PV = nRT \] Rearranging gives: \[ T = \frac{PV}{nR} \] 4. **Substituting for \( T \)**: We can substitute \( T \) from the ideal gas law into our earlier equation: \[ \frac{PV}{nR} \cdot V^{2/7} = k \] Simplifying gives: \[ PV^{9/7} = nRk \] This indicates that \( PV^{9/7} \) is also a constant. 5. **Analyzing Heat Transfer**: When heat \( Q \) is added to the system, the first law of thermodynamics states: \[ Q = \Delta U + W \] where \( \Delta U \) is the change in internal energy and \( W \) is the work done by the gas. 6. **Change in Internal Energy**: For a monatomic gas, the change in internal energy is given by: \[ \Delta U = \frac{3}{2} nR \Delta T \] 7. **Work Done by the Gas**: The work done by the gas can be expressed as: \[ W = P \Delta V \] Using the relationship from earlier, we can find how \( W \) changes with \( \Delta T \). 8. **Determining the Effect of Heat**: As heat is supplied, the temperature \( T \) increases. However, since \( T \) is proportional to \( V^{-2/7} \), an increase in \( T \) implies a decrease in \( V \) (the volume must decrease to maintain the relationship). 9. **Density Consideration**: Density \( \rho \) is defined as: \[ \rho = \frac{m}{V} \] If the volume decreases while mass remains constant, the density increases. 10. **Identifying the Incorrect Option**: Based on the analysis: - If the gas expands, the work done by the gas is positive. - If the temperature decreases, the RMS velocity decreases. - If the volume decreases, the density increases. Therefore, the incorrect statement would be the one that suggests that the density of the gas decreases when heat is supplied.
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