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Photons emitted by a gas consisting of excited hydrogen like atoms (A) during a transition from a higher quantum state (quantum no. n) to a lower quantum state (quantum no :m ) are incident on a metallic surface (B) causing the emission of photoelectrons . The fastest photoelectrons pass undeviated through a region consisting of electric field `E_0 =3.7` V/cm and magnetic field `B_0 =10^3`T , oriented in perpecdicular directions and the photoelctrons enter the region perpendicular to both the electric and magnetic field
The threshold wavelength for the metal B equal 830 nm. the spectrum of radiations emitted by the excited hydrogen -like atoms (A) consists of 15 different wavelengths .
Find the quantum numbers of the states n,m and atomic number (Z) of the element (A) . (Take `1.89//13.6~~1//7)`

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To solve the given problem, we need to analyze the situation involving the hydrogen-like atoms and the photoelectrons emitted from the metallic surface. Here’s a step-by-step solution: ### Step 1: Understand the Photon Emission When the hydrogen-like atoms transition from a higher quantum state (n) to a lower quantum state (m), they emit photons. The energy of the emitted photons can be calculated using the formula: \[ E = -13.6 \frac{Z^2}{n^2} + 13.6 \frac{Z^2}{m^2} \] Where \( Z \) is the atomic number of the hydrogen-like atom. ### Step 2: Calculate the Energy of the Photons The energy of the emitted photons must also satisfy the photoelectric effect condition, where the energy of the photon must be greater than the work function of the metal. The work function \( \phi \) can be calculated from the threshold wavelength \( \lambda_0 \): \[ \phi = \frac{hc}{\lambda_0} \] Where: - \( h \) is Planck's constant (\( 6.626 \times 10^{-34} \, \text{Js} \)) - \( c \) is the speed of light (\( 3 \times 10^8 \, \text{m/s} \)) - \( \lambda_0 = 830 \, \text{nm} = 830 \times 10^{-9} \, \text{m} \) Calculating \( \phi \): \[ \phi = \frac{(6.626 \times 10^{-34})(3 \times 10^8)}{830 \times 10^{-9}} \approx 2.4 \times 10^{-19} \, \text{J} \] ### Step 3: Relate Photon Energy to Quantum States The energy of the emitted photon must be equal to or greater than the work function: \[ E \geq \phi \] Substituting the expression for \( E \): \[ -13.6 \frac{Z^2}{n^2} + 13.6 \frac{Z^2}{m^2} \geq 2.4 \times 10^{-19} \] ### Step 4: Determine the Number of Wavelengths The problem states that there are 15 different wavelengths emitted. The number of spectral lines in a transition from level \( n \) to level \( m \) is given by: \[ N = n - m \] Setting \( n - m = 15 \) gives us: \[ n = m + 15 \] ### Step 5: Solve for Quantum Numbers Substituting \( n \) in the energy equation, we have: \[ -13.6 \frac{Z^2}{(m + 15)^2} + 13.6 \frac{Z^2}{m^2} \geq 2.4 \times 10^{-19} \] ### Step 6: Use Given Data From the problem, we have \( \frac{1.89}{13.6} \approx \frac{1}{7} \). This suggests \( Z \) can be estimated. Assuming \( Z = 7 \): \[ -13.6 \frac{7^2}{(m + 15)^2} + 13.6 \frac{7^2}{m^2} \geq 2.4 \times 10^{-19} \] ### Step 7: Calculate Specific Values Now, we can try different values for \( m \) (starting from 1 upwards) and check if the inequality holds true. For example, if \( m = 1 \): \[ n = 16 \] Calculating the energies: \[ E = -13.6 \cdot \frac{49}{256} + 13.6 \cdot \frac{49}{1} = 13.6 \cdot 49 \left(1 - \frac{49}{256}\right) \] Calculating gives a value that can be compared to \( 2.4 \times 10^{-19} \). ### Conclusion After checking various values, we find that \( n = 16 \), \( m = 1 \), and \( Z = 7 \) satisfy the conditions. ### Final Answer - Quantum numbers: \( n = 16, m = 1 \) - Atomic number \( Z = 7 \)
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