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One mole of monoatomic gas and one mole ...

One mole of monoatomic gas and one mole of diatomic gas are mixed together. What is the molar specific heat at constant volume for the mixture ?

A

3/2R

B

2R

C

5/2R

D

3R

Text Solution

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The correct Answer is:
To find the molar specific heat at constant volume for a mixture of one mole of monoatomic gas and one mole of diatomic gas, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Gases**: We have one mole of a monoatomic gas and one mole of a diatomic gas. 2. **Determine Degrees of Freedom**: - For a monoatomic gas, the degrees of freedom (F) is 3. - For a diatomic gas, the degrees of freedom (F) is 5. 3. **Calculate Cv for Each Gas**: - The formula for molar specific heat at constant volume (Cv) is given by: \[ C_v = \frac{1}{2} F R \] - For the monoatomic gas: \[ C_{v1} = \frac{1}{2} \times 3 \times R = \frac{3}{2} R \] - For the diatomic gas: \[ C_{v2} = \frac{1}{2} \times 5 \times R = \frac{5}{2} R \] 4. **Use the Formula for Mixture**: - The molar specific heat at constant volume for the mixture (C_v) can be calculated using the formula: \[ C_v = \frac{N_1 C_{v1} + N_2 C_{v2}}{N_1 + N_2} \] - Here, \(N_1\) and \(N_2\) are the number of moles of the monoatomic and diatomic gases, respectively. Since both are 1 mole: \[ C_v = \frac{1 \cdot \frac{3}{2} R + 1 \cdot \frac{5}{2} R}{1 + 1} \] 5. **Calculate the Mixture's Cv**: - Substitute the values: \[ C_v = \frac{\frac{3}{2} R + \frac{5}{2} R}{2} = \frac{\frac{8}{2} R}{2} = \frac{8R}{4} = 2R \] 6. **Conclusion**: - The molar specific heat at constant volume for the mixture of one mole of monoatomic gas and one mole of diatomic gas is: \[ C_v = 2R \]
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