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For a hypothetical reaction, A+B to C+D,...

For a hypothetical reaction, `A+B to C+D`, the rate `=k[A]^(-1//2)[B]^(3//2)`. On doubling the concentration of A and B the rate will be

A

`4` times

B

`2` times

C

`3` times

D

none of the above

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze how the rate of the reaction changes when the concentrations of reactants A and B are doubled. ### Step-by-Step Solution: 1. **Write the initial rate expression**: The rate of the reaction is given by: \[ \text{Rate} = k[A]^{-1/2}[B]^{3/2} \] where \( k \) is the rate constant, and \([A]\) and \([B]\) are the concentrations of A and B, respectively. 2. **Define the initial concentrations**: Let the initial concentrations of A and B be \([A] = a\) and \([B] = b\). Therefore, the initial rate \( R_1 \) can be expressed as: \[ R_1 = k[a]^{-1/2}[b]^{3/2} \] 3. **Determine the new concentrations after doubling**: When the concentrations of A and B are doubled, we have: \[ [A] = 2a \quad \text{and} \quad [B] = 2b \] 4. **Substitute the new concentrations into the rate expression**: The new rate \( R_1' \) when the concentrations are doubled becomes: \[ R_1' = k[2a]^{-1/2}[2b]^{3/2} \] 5. **Simplify the new rate expression**: \[ R_1' = k(2a)^{-1/2}(2b)^{3/2} \] This can be simplified as: \[ R_1' = k \cdot \frac{1}{(2^{1/2} \cdot a^{1/2})} \cdot (2^{3/2} \cdot b^{3/2}) \] \[ R_1' = k \cdot \frac{2^{3/2}}{2^{1/2}} \cdot \frac{b^{3/2}}{a^{1/2}} = k \cdot 2^{3/2 - 1/2} \cdot [a]^{-1/2}[b]^{3/2} \] \[ R_1' = k \cdot 2^{2/2} \cdot [a]^{-1/2}[b]^{3/2} = k \cdot 2 \cdot [a]^{-1/2}[b]^{3/2} \] 6. **Relate the new rate to the initial rate**: Thus, we can express the new rate as: \[ R_1' = 2 \cdot R_1 \] 7. **Conclusion**: Therefore, when the concentrations of A and B are doubled, the rate of the reaction becomes: \[ R_1' = 2R_1 \] This means the rate will be **2 times** the initial rate. ### Final Answer: The rate will be **2 times** the initial rate.
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