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Haloalkanes undergo nucleophilic substit...

Haloalkanes undergo nucleophilic substitution reactions while haloarenes undergo electrophilic substitution reactions. Explian.

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The various electrophilic substitution reactions follow three steps. These are given as below:
i) Generation of electrophile `(Y^(+))` : The electrophile is generated by dissociation of a reagent say XY under suitable conditions. `X - Y overset("Dissociation")to Y^(+) + :X^(-)`
ii) Attack of electrophile: In this step, electrophile attaks on the `pi`-electron cloud of aromatic ring. The formation of arenium ion or `sigma`-complex takes place which is stabilised by resonance.

iii)Removal of proton: In this step, nucleophile abstracts a proton from the intermediate carbocation. This results in the formation of substituted product.
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Knowledge Check

  • Nucleophilic addition reactions are catalyzed by:

    A
    Acid
    B
    Base
    C
    Both (a) and (b)
    D
    None
  • Towards electrophilic substitution, the most reactive will be

    A
    Nitrobenzene
    B
    Aniline
    C
    Aniline hydrochloride
    D
    N-Acetylaniline
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