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Osmotic Pressure (pi)....

Osmotic Pressure `(pi)`.

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Osmosis is the phenomenon of spontaneous flow of the solvent molecules through a semipermeable membrane from pure solvent to solution or from a dilute solution to concentrated solution. It was first observed by Abbe Nollet.
Osmosis may be
(i) Exosmosis : It is outward flow of water or solvent from a cell through semipermeable membrane.
(ii) Endosmosis : It is inward flow of water or solvent from a cell through a semipermeable membrane. The hydrostatic pressure developed on the solution which just prevents the osmosis of pure solvent into the solution through a semipermeable membrane is called
Osmotic pressure `(pi) =RCT , (C=n_B /V =(W_B)/(M_BV))`
`M_B = (W_BRT)/(piV)`
`pi = (dRT)/(M_B), (d=W_B/V)`
where, d = density, R = solution constant, T = temperature, `M_B` = molar mass of solute.
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van't Hoff proved that osmotic pressure ( pi ) is a colligative property. For an ideal solution, osmotic pressure( pi ) is helpful to determine that molecular mass of solute using M_(B)=(W_(B)RT)/(pi.V) Relation can exxpressed by the curve (C = concentration) :

Insulin (C_(2)H_(10)O_(5))_(n) is dissolved in a suitable solvent and the osmotic pressure (pi) of solutions of various concentrations (g//cm^(3))C is measured at 20^(@)C . The slope of a plot of pi against C is found to be 4.65 xx 10^(-3) . The molecular weight of insulin is:

Differentiate between the following: Osmotic Pressure and Osmotice Potential

Each question contains STATEMENT-I(Assertion) and STATEMENT-2(Reason).the statement carefully and mark the correct answer accoring to the instrution given below: STATEMENT - 1 : Osmotic pressure is a colligative property. STATEMENT - 2 : Osmotic pressure is developed in a column due to osmosis.

Determine the amount of CaCl_2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27° C.

An aqueous solution of urea has a freezing point of -0.515^(@)C . Predict the osmotic pressure (in atm) of the same solution at 37^(@)C .

What is Osmotic pressure?

Osmotic pressure of a solution is

ACCURATE PUBLICATION-SOLUTIONS -3 MARK QUESTION
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  7. What is a semi-permeable membrane ?

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  12. Do molality and mole fraction changes with temperature ?

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  17. How will you show that depression in freezing point is a colligative p...

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  18. Osmotic Pressure (pi).

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  19. Write differences between ideal and non-ideal solutions.

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  20. Write differences between ideal and non-ideal solutions.

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