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Under the influence for an electric fiel...

Under the influence for an electric field, the particles in a sol migrate towards cathode . The coagulation of the same sol is studied using NaCl, `Na_(2) SO_(4) and Na_(3)PO_(4)` solutions. Their coagulating values will be in maximum for :

A

`NaCl gt BaCl_(2) gt AlCl_(3)`

B

`BaCl_(2) gt AlCl_(3) gt NaCl`

C

`AlCl_(3) gt BaCl_(2) gt NaCl`

D

`BaCl_(2) gt NaCl gt AlCl_(3)`

Text Solution

Verified by Experts

The correct Answer is:
C
The movement towards positive electrode shows that sol is negative. For coagulation of negative sol. Cation with higher charge is more effective.
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Under the influemce of an electric field, the particles in a sol migrate towards cathode. The coagulation of the same sol is studied using NaCl,Na_(2)SO_(4) , and Na_(3)PO_(4) solutions. Their coagulation values will in the order a. NaClgtNa_(2)SO_(4)gtNa_(3)PO_(4) b. Na_(2)SO_(4)gtNa_(3)PO_(4)gtNaCl c. Na_(3)PO_(4)gtNa_(2)SO_(4)gtNaCl d. Na_(2)SO_(4)gtNaClgtNa_(3)PO_(4)

A colloidal solution is a type of mixture which consists of particles whose size varies between 1 and 1000 nanometres. In colloidal solution the particles are distributed evenly. During this process the particles do not settle down. This is one of the best know thing about colloidal solutions. Properties of colloids and their variation are a well-known area ever since the primitive age. The best example to prove their familiarity with us is that we know from very early times that coagulation of milk results in the formation of curd. Physical properties of colloids 1. The nature of the colloidal solution is heterogeneous i.e. unlike. These solutions dwell with two different phases : • Dispersed medium Dispersed phase. 2. Despite the fact that colloidal dispersions are unlike in description (nature), yet the dispersed fragments are not detectable by the human eye. This is due to the microscopic size of the particles in the solution. 3. The colour of the colloidal dispersion is determined by particles in the solution based on their size. The wavelengths of light that is absorbed will be longer ifthe size of the particle is large. 4. As a result of its size, the colloidal fragments can easily be passed through a traditional filter paper. However, these particles can be filtered by using membranes such as animal, cellophane, and ultrafilters. What are colloidal solution particle.

A colloidal solution is a type of mixture which consists of particles whose size varies between 1 and 1000 nanometres. In colloidal solution the particles are distributed evenly. During this process the particles do not settle down. This is one of the best know thing about colloidal solutions. Properties of colloids and their variation are a well-known area ever since the primitive age. The best example to prove their familiarity with us is that we know from very early times that coagulation of milk results in the formation of curd. Physical properties of colloids 1. The nature of the colloidal solution is heterogeneous i.e. unlike. These solutions dwell with two different phases : • Dispersed medium Dispersed phase. 2. Despite the fact that colloidal dispersions are unlike in description (nature), yet the dispersed fragments are not detectabJe by the human eye. This is due to the microscopic size of the particles in the solution. 3. The colour of the colloidal dispersion is determined by particles in the solution based on their size. The wavelengths of light that is absorbed will be longer ifthe size of the particle is large. 4. As a result of its size, the colloidal fragments can easily be passed through a traditional filter paper. However, these particles can be filtered by using membranes such as animal, cellophane, and ultrafilters. Give the name of membrane used for filteration ?

A colloidal solution is a type of mixture which consists of particles whose size varies between 1 and 1000 nanometres. In colloidal solution the particles are distributed evenly. During this process the particles do not settle down. This is one of the best know thing about colloidal solutions. Properties of colloids and their variation are a well-known area ever since the primitive age. The best example to prove their familiarity with us is that we know from very early times that coagulation of milk results in the formation of curd. Physical properties of colloids 1. The nature of the colloidal solution is heterogeneous i.e. unlike. These solutions dwell with two different phases : • Dispersed medium Dispersed phase. 2. Despite the fact that colloidal dispersions are unlike in description (nature), yet the dispersed fragments are not detectabJe by the human eye. This is due to the microscopic size of the particles in the solution. 3. The colour of the colloidal dispersion is determined by particles in the solution based on their size. The wavelengths of light that is absorbed will be longer ifthe size of the particle is large. 4. As a result of its size, the colloidal fragments can easily be passed through a traditional filter paper. However, these particles can be filtered by using membranes such as animal, cellophane, and ultrafilters. What type of phases of colloidal solutions ?

The coagulation values in millimoles per litre of the electrolytes used for the coagulation of As_2S_3 are given: I. (NaCl)= 52, II. (BaCl_2) = 0.69 , III. (MgSO_4) = 0.22. The correct order of their coagulating power is

which of the following statement is / are correct for electrophoresis : Colloidal are uncharged particles and do not migrate towards the electrodes when electric field is applied, In electrophoresis , sol migrates either to the anode or to the cathode depending on the positively or negatively charged sol, Electrophoresis is useful for finding the charge on a sol, all of these.

Arrange the following electrolytes in the increasing order of coagulation power for the coagulation of As_(2)S_(3) sol : K_(2)SO_(4) " " CaCl_(2)" " Na_(3)PO_(4) " " AlCl_(3) : Ilt II lt IIIlt IV , I=III lt II lt IV , II lt IV lt I lt II , II lt III lt IV lt I .

Read the given passage and answers following questions : The particles of colloidal solution possess electrical charge which is responsible for the stability of these solutions. The charge on colloidal particles arises because of selective adsorption of ions which are common with their own lattice. The presence of charge on colloidal particles can be determined with the help of phenomenon known as electrophoresis. However, when some electrolyte is added, the charge on the particles of, dispersed phase gets neutralized and precipitation takes place. This process is also called coagulation. The coagulation is given by Hardy Schulze rules. According to these rules the ions carrying the charge opposite to that of sol particles are effective and coagulating power of an electrolyte is directly proportional to the fourth power of the valency of the ion. Coagulation can also occur by mutual precipitation , by electrophoresis, by persistent dialysis or by heating or cooling. Answer the following questions : Which electrolyte is most effective for coagulating Fe(OH)3 sol?

The existence of negatively charged particle in an atom was shown by J.J. Thomson as a result of the studies of the passage of electricity through gases at extremely low pressure known as discharge tube experiments. When a high voltage of the order of 10,000 volts or more was impressed across the electrodes, some sort of invisible rays moved from the negative electrode to the positive electrode these rays are called as cathode rays. Cathode rays travel in straight path in absence of electrical and magnetic field . Cathode rays consist of material part and charged particles? Cathode rays produce X-rays and light is emitted when they strike on ZnS screen. Cathode rays penetrate through thin sheets of aluminium and other metals . They affect the photogenic plate and passes heating effect when they strike on metal foil. The raito of charge to mass i.e charge/mass is same for all the cathode rays irrespective of the gas used in the tube. The existence of positively charged particle in an atom was shown be E. Goldstein. He repeated the same discharge tube experiments by using a perforated cathode. It was observed that when a high potential difference was applied between the electrodes, not only cathode rays were produced but also a new type of rays were produced simultaneoulsy from anode moving towards cathode and passes through the holes or canal of the cathode. These termed as canal rays or anode rays. These rays travel in straight lines and consists of positively charged particles. These rays have kinetic energy and produces heating effect also. The e/m ratio of these rays is smaller than that of electrons. Unlike cathode rays, their e/m value is dependent upon the nature of the gas taken in the tube. These rays produced flashes of light on ZnS screen and can pass throughs thin metal foils. They can produce physical and chemical changes and are capable to produce ionisation in gases. For cathode rays the value of e/m:

The existence of negatively charged particle in an atom was shown by J.J. Thomson as a result of the studies of the passage of electricity through gases at extremely low pressure known as discharge tube experiments. When a high voltage of the order of 10,000 volts or more was impressed across the electrodes, some sort of invisible rays moved from the negative electrode to the positive electrode these rays are called as cathode rays. Cathode rays travel in straight path in absence of electrical and magnetic field . Cathode rays consist of material part and charged particles? Cathode rays produce X-rays and light is emitted when they strike on ZnS screen. Cathode rays penetrate through thin sheets of aluminium and other metals . They affect the photogenic plate and passes heating effect when they strike on metal foil. The raito of charge to mass i.e charge/mass is same for all the cathode rays irrespective of the gas used in the tube. The existence of positively charged particle in an atom was shown be E. Goldstein. He repeated the same discharge tube experiments by using a perforated cathode. It was observed that when a high potential difference was applied between the electrodes, not only cathode rays were produced but also a new type of rays were produced simultaneoulsy from anode moving towards cathode and passes through the holes or canal of the cathode. These termed as canal rays or anode rays. These rays travel in straight lines and consists of positively charged particles. These rays have kinetic energy and produces heating effect also. The e/m ratio of these rays is smaller than that of electrons. Unlike cathode rays, their e/m value is dependent upon the nature of the gas taken in the tube. These rays produced flashes of light on ZnS screen and can pass throughs thin metal foils. They can produce physical and chemical changes and are capable to produce ionisation in gases. Which is not true with respect to cathode rays?

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